Assessment of migrating endocrine-disrupting chemicals in bottled acidic juice using type UVM-7 mesoporous silica modified with cyclodextrin

An innovative material based in type UVM-7 mesoporous silica containing analyte-accessible cyclodextrin units is described and assessed as a selectivity-enhancing sorbent for extracting endocrine-disrupting chemicals from bottled apple juice to subsequently quantify them. The synthesis procedure has been carried out using both β- and γ-cyclodextrin for their later comparison. Then, a complete analytical method for the isolation and determination of the above analytes has been validated. Following the optimized procedure, recoveries between 94% and 100% have been achieved and good repeatability is obtained with deviations under 6.8% for intra-day and inter-day experiments. The detection limits of the method have been established in the ng L-1 level, which demonstrates the ability to quantify the trace concentrations established by sanitary restrictions. A low matrix effect is found when working with real samples. To end, a comparison with an alternative extraction method using C18 extraction cartridges has been carried out and the results obtained with both procedures are comparable