Strain-Promoted Cycloaddition of Cyclopropenes with o-Quinones: A Rapid Click Reaction

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2018
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Abstract
Novel click reactions are of continued interest in fields as diverse as bio-conjugation, polymer science and surface chemistry. Qualification as a proper 'click' reaction requires stringent criteria, including fast kinetics and high conversion, to be met. Herein, we report a novel strain-promoted cycloaddition between cyclopropenes and o-quinones in solution and on a surface. We demonstrate the 'click character' of the reaction in solution and on surfaces for both monolayer and polymer brush functionalization.
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Gahtory, Digvijay Sen, Rickdeb Kuzmyn, Andriy R. Escorihuela Fuentes, Jorge Zuilhof, Han 2018 Strain-Promoted Cycloaddition of Cyclopropenes with o-Quinones: A Rapid Click Reaction Angewandte Chemie 57 32 10118 10122
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