Mg/BOX complexes as efficient catalysts for the enantioselective Michael addition of malonates to β-trifluoromethyl-α,β-unsaturated ketones and their N-tosyl imines
NAGIOS: RODERIC FUNCIONANDO

Mg/BOX complexes as efficient catalysts for the enantioselective Michael addition of malonates to β-trifluoromethyl-α,β-unsaturated ketones and their N-tosyl imines

DSpace Repository

Mg/BOX complexes as efficient catalysts for the enantioselective Michael addition of malonates to β-trifluoromethyl-α,β-unsaturated ketones and their N-tosyl imines

Show full item record

View       (304.9Kb)

Exportar a Refworks
    
Espinosa López, Miguel; Iborra-Torres, Antonio; Sanz Marco, Amparo; Blay Llinares, Gonzalo Perfil; Cardona Prósper, María Luz; Fernández Picot, Isabel; Pedro, José Ramón
This document is a artículoDate2021
Magnesium (II)-BOX complexes catalyze the enantioselective Michael addition of malonates to β-trifluoromethyl enones and their N-sulfonyl imines to give ketones or (E)-enamines bearing a trifluoromethylated stereogenic center, respectively, with good yields and high enantiomeric excesses. Magnesium complexes proved to be more active and stereoselective than zinc and copper analogues in these reactions.

    Espinosa López, Miguel Iborra-Torres, Antonio Sanz Marco, Amparo Blay Llinares, Gonzalo Cardona Prósper, María Luz Fernández Picot, Isabel Pedro, José Ramón 2021 Mg/BOX complexes as efficient catalysts for the enantioselective Michael addition of malonates to β-trifluoromethyl-α,β-unsaturated ketones and their N-tosyl imines Tetrahedron 80 131897
https://doi.org/10.1016/j.tet.2020.131897

This item appears in the following Collection(s)

Show full item record

Search DSpace

Advanced Search

Browse

Statistics