Custom Coordination Environments for Lanthanoids: Tripodal Ligands Achieve Near-Perfect Octahedral Coordination for Two Dysprosium-Based Molecular Nanomagnets
NAGIOS: RODERIC FUNCIONANDO

Custom Coordination Environments for Lanthanoids: Tripodal Ligands Achieve Near-Perfect Octahedral Coordination for Two Dysprosium-Based Molecular Nanomagnets

DSpace Repository

Custom Coordination Environments for Lanthanoids: Tripodal Ligands Achieve Near-Perfect Octahedral Coordination for Two Dysprosium-Based Molecular Nanomagnets

Show full item record

View       (14.51Mb)

Exportar a Refworks
    
Soo Lim, Kwang; Baldoví, José J. Perfil; Jiang, ShangDa; Koo, Bong Ho; Kang, Dong Won; Lee, Woo Ram; Koh, Eui Kwan; Gaita Ariño, Alejandro Perfil; Coronado Miralles, Eugenio Perfil; Slota, Michael; Bogani, Lapo; Hong, Chang Seop
This document is a artículoDate2017
Controlling the coordination sphere of lanthanoid complexes is a challenging critical step toward controlling their relaxation properties. Here we present the synthesis of hexacoordinated dysprosium single-molecule magnets, where tripodal ligands achieve a near-perfect octahedral coordination. We perform a complete experimental and theoretical investigation of their magnetic properties, including a full single-crystal magnetic anisotropy analysis. The combination of electrostatic and crystal-field computational tools (SIMPRE and CONDON codes) allows us to explain the static behavior of these systems in detail.

    Kwang Soo Lim, José J. Baldoví, ShangDa Jiang, Bong Ho Koo, Dong Won Kang, Woo Ram Lee, Eui Kwan Koh, Alejandro Gaita-Ariño, Eugenio Coronado, Michael Slota, Lapo Bogani, Chang Seop Hong, Inorg. Chem. 2017, 56, 9, 4911–4917
https://doi.org/10.1021/acs.inorgchem.6b03118

This item appears in the following Collection(s)

Show full item record

Search DSpace

Advanced Search

Browse

Statistics