NAGIOS: RODERIC FUNCIONANDO

Magnesium Exchanged Zirconium Metal−Organic Frameworks with Improved Detoxification Properties of Nerve Agents

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	Gil-San-Millan, Rodrigo; López Maya, Elena; ́Platero-Prats, Ana E.; Torres-Pérez, Virginia; Delgado, Pedro; ́Augustyniak, Adam W.; Kim, Min Kun; Lee, Hae Wan; Ryu, Sam Gon; Navarro, Jorge A. R.
	This document is a artículoDate2019
	UiO-66, MOF-808 and NU-1000 metal-organic frameworks exhibit a differentiated reactivity toward [Mg(OMe)2(MeOH)2]4 related to their pore accessibility. Microporous UiO-66 remains unchanged while mesoporous MOF-808 and hierarchical micro/mesoporous NU-1000 materials yield doped systems containing exposed MgZr5O2(OH)6 clusters in the mesoporous cavities. This modification is responsible for a remarkable enhancement of the catalytic activity toward the hydrolytic degradation of P-F and P-S bonds of toxic nerve agents, at room temperature, in unbuffered aqueous solutions.
	Gil-San-Millan, Rodrigo López Maya, Elena &#769Platero-Prats, Ana E. Torres-Pérez, Virginia Delgado, Pedro &#769Augustyniak, Adam W. Kim, Min Kun Lee, Hae Wan Ryu, Sam Gon Navarro, Jorge A. R. 2019 Magnesium Exchanged Zirconium Metal−Organic Frameworks with Improved Detoxification Properties of Nerve Agents Journal of the American Chemical Society 141 30 11801 11805
	https://doi.org/10.1021/jacs.9b05571