NAGIOS: RODERIC FUNCIONANDO
Direct catalytic cross-coupling of alkenyllithium compounds
DSpace Repository
- DSpace Home
- Investigació
- e-prints
- 23 - Química
- View Item
Direct catalytic cross-coupling of alkenyllithium compounds
|
View
|
|
| Hornillos, Valentín; Giannerini, Massimo; Vila Descals, Carlos; Fañanás-Mastral, Martín; Feringa, Ben L. | |
| This document is a artículoDate2015 | |
| A catalytic method for the direct cross-coupling of alkenyllithium reagents with aryl and alkenyl halides is described. The use of a catalyst comprising Pd2(dba)3/XPhos allows for the stereoselective preparation of a wide variety of substituted alkenes in high yields under mild conditions. In addition (1-ethoxyvinyl)lithium can be efficiently converted into substituted vinyl ethers which, after hydrolysis, give readily access to the corresponding methyl ketones in a one pot procedure. | |
|
Hornillos, Valentín Giannerini, Massimo Vila Descals, Carlos Fañanás-Mastral, Martín Feringa, Ben L. 2015 Direct catalytic cross-coupling of alkenyllithium compounds Chemical Science 6 2 1394 1398 |
|
| https://doi.org/10.1039/C4SC03117B |
This item appears in the following Collection(s)
-
23 - Química [887]