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A highly stable and hierarchical tetrathiafulvalene-based metal-organic framework with improved performance as a solid catalyst

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	Souto González, Xosé M. Perfil; Santiago-Portillo, Andrea; Palomino, Miguel; Vitórica-Yrezábal, Iñigo J.; Vieira, Bruno J. C.; Waerenborgh, João C.; Valencia, Susana; Navalón, Sergio; Rey, Fernando; García, Hermenegildo; Mínguez Espallargas, Guillermo
	This document is a artículoDate2018
	Este documento está disponible también en : http://hdl.handle.net/10550/68319
	Herein we report the synthesis of a tetrathiafulvalene (TTF)-based MOF, namely MUV-2, which shows a non-interpenetrated hierarchical crystal structure with mesoporous one-dimensional channels of ca. 3 nm and orthogonal microporous channels of ca. 1 nm. This highly stable MOF (aqueous solution with pH values ranging 2-11 and different organic solvents), possessing the well-known [Fe3(μ3-O)(COO)6] secondary building unit, has proven to be an efficient catalyst for the aerobic oxidation of dibenzothiophenes.
	Souto, Manuel Santiago-Portillo, Andrea Palomino, Miguel Vitórica-Yrezábal, Iñigo J. Vieira, Bruno J. C. Waerenborgh, João C. Valencia, Susana Navalón, Sergio Rey, Fernando García, Hermenegildo Mínguez Espallargas, Guillermo 2018 A highly stable and hierarchical tetrathiafulvalene-based metal-organic framework with improved performance as a solid catalyst Chemical Science 9 2413 2418
	https://doi.org/10.1039/C7SC04829G