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Heterometallic palladium-iron metal-organic framework as a highly active catalyst for cross-coupling reactions

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Heterometallic palladium-iron metal-organic framework as a highly active catalyst for cross-coupling reactions

dc.contributor.author	Miguel-Casañ, Eugenia
dc.contributor.author	Darawsheh, Mohanad D.
dc.contributor.author	Fariña-Torres, Víctor
dc.contributor.author	Vitórica-Yrezábal, Iñigo J.
dc.contributor.author	Andres-Garcia, Eduardo
dc.contributor.author	Fañanás-Mastral, Martín
dc.contributor.author	Mínguez Espallargas, Guillermo
dc.date.accessioned	2023-01-09T15:17:28Z
dc.date.available	2023-01-09T15:17:28Z
dc.date.issued	2023
dc.identifier.uri	https://hdl.handle.net/10550/84919
dc.description.abstract	Palladium-based metal-organic frameworks (Pd-MOFs) are an emerging class of heterogeneous catalysts extremely challenging to achieve due to the facile leaching of palladium and its tendency to be reduced. Herein, Pd(II) was successfully incorporated in the framework of a MOF denoted as MUV-22 using a solvent assisted reaction. This stable MOF, with square-octahedron (soc) topology as MIL-127, and a porosity of 710 m2 g−1, is highly active, selective, and recyclable for the Suzuki-Miyaura allylation of aryl and alkyl boronates as exemplified with the coupling between cinnamyl bromide and Me-Bpin, a typically reluctant reagent in cross-coupling reactions.
dc.language.iso	eng
dc.relation.ispartof	Chemical Science, 2023, vol. 14, num. 1, p. 179-185
dc.source	Miguel-Casañ, Eugenia Darawsheh, Mohanad D. Fariña-Torres, Víctor Vitórica-Yrezábal, Iñigo J. Andres-Garcia, Eduardo Fañanás-Mastral, Martín Mínguez Espallargas, Guillermo 2023 Heterometallic palladium-iron metal-organic framework as a highly active catalyst for cross-coupling reactions Chemical Science 14 1 179 185
dc.subject	Reaccions químiques
dc.subject	Metalls de transició
dc.title	Heterometallic palladium-iron metal-organic framework as a highly active catalyst for cross-coupling reactions
dc.type	journal article	es_ES
dc.date.updated	2023-01-09T15:17:29Z
dc.identifier.doi	https://doi.org/10.1039/D2SC05192C
dc.identifier.idgrec	156249
dc.rights.accessRights	open access	es_ES