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Radical Addition of Dihydroquinoxalin-2-ones to Trifluoromethyl Ketones under Visible-Light Photoredox Catalysis

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Radical Addition of Dihydroquinoxalin-2-ones to Trifluoromethyl Ketones under Visible-Light Photoredox Catalysis

dc.contributor.author	Rostoll Berenguer, Jaume
dc.contributor.author	Martín-López, María
dc.contributor.author	Blay Llinares, Gonzalo
dc.contributor.author	Pedro, José Ramón
dc.contributor.author	Vila Descals, Carlos
dc.date.accessioned	2022-11-29T13:34:51Z
dc.date.available	2022-11-29T13:34:51Z
dc.date.issued	2022
dc.identifier.uri	https://hdl.handle.net/10550/84619
dc.description.abstract	A visible-light photocatalytic radical addition reaction of dihydroquinoxalin-2-ones to trifluoromethyl ketones has been established using Ru(bpy)3Cl2 as photocatalyst, acetonitrile as solvent, and HP Single Blue LED as the source of light. The reaction provides a straightforward approach to the synthesis of dihydroquinoxalin-2-ones bearing a trifluoromethyl-substituted tertiary alcohol moiety in moderate to good yields under mild conditions.
dc.language.iso	eng
dc.relation.ispartof	Journal of Organic Chemistry, 2022, vol. 87, num. 14, p. 9343-9356
dc.rights.uri	info:eu-repo/semantics/openAccess
dc.source	Rostoll Berenguer, Jaume Martín-López, María Blay Llinares, Gonzalo Pedro, José Ramón Vila Descals, Carlos 2022 Radical Addition of Dihydroquinoxalin-2-ones to Trifluoromethyl Ketones under Visible-Light Photoredox Catalysis Journal of Organic Chemistry 87 14 9343 9356
dc.subject	Química orgànica
dc.subject	Reaccions químiques
dc.title	Radical Addition of Dihydroquinoxalin-2-ones to Trifluoromethyl Ketones under Visible-Light Photoredox Catalysis
dc.type	info:eu-repo/semantics/article
dc.date.updated	2022-11-29T13:34:52Z
dc.identifier.doi	https://doi.org/10.1021/acs.joc.2c01139
dc.identifier.idgrec	154353