A fluorinated 2D magnetic coordination polymer

A fluorinated 2D magnetic coordination polymer

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A fluorinated 2D magnetic coordination polymer

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López Cabrelles, Javier; Mañas Valero, Samuel; Vitórica-Yrezábal, Iñigo J.; Bereciartua, P. J.; Coronado Miralles, Eugenio Perfil; Mínguez Espallargas, Guillermo
This document is a artículoDate2022
Herein we show the versatility of coordination chemistry to design and expand a family of 2D materials by incorporating F groups at the surface of the layers. Through the use of a prefuntionalized organic linker with F groups, it is possible to achieve a layered magnetic material based on Fe(II) centers that are chemically stable in open air, contrary to the known 2D inorganic magnetic materials. The high quality of the single crystals and their robustness allow to fabricate 2D molecular materials by micromechanical exfoliation, preserving the crystalline nature of these layers together with the desired functionalization.

    López Cabrelles, Javier Mañas Valero, Samuel Vitórica-Yrezábal, Iñigo J. Bereciartua, P. J. Coronado Miralles, Eugenio Mínguez Espallargas, Guillermo 2022 A fluorinated 2D magnetic coordination polymer Dalton Transactions 51 1861 1865

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