Multivariate sodalite zeolitic imidazolate frameworks: a direct solvent-free synthesis
NAGIOS: RODERIC FUNCIONANDO

Multivariate sodalite zeolitic imidazolate frameworks: a direct solvent-free synthesis

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Multivariate sodalite zeolitic imidazolate frameworks: a direct solvent-free synthesis

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López Cabrelles, Javier; Miguel‐Casañ, Eugenia; Esteve-Rochina, María; Andres-Garcia, Eduardo; Vitórica-Yrezábal, Iñigo J.; Calbo Roig, Joaquín; Mínguez Espallargas, Guillermo
This document is a artículoDate2022
Different mixed-ligand Zeolitic Imidazolate Frameworks (ZIFs) with sodalite topology, i.e. isoreticular to ZIF-8, unachievable by conventional synthetic routes, have been prepared using a solvent-free methodology. In particular, the versatility of this method is demonstrated with three different metal centres (Zn, Co and Fe) and binary combinations of three different ligands (2-methylimidazole, 2-ethylimidazole and 2-methylbenzimidazole). One combination of ligands, 2-ethylimidazole and 2-methylbenzimidazole, results in the formation of SOD frameworks for the three metal centres despite this topology not being obtained for the individual ligands. Theoretical calculations confirm that this topology is the lowest in energy upon ligand mixing.

    López Cabrelles, Javier Miguel&#8208Casañ, Eugenia Esteve-Rochina, María Andres-Garcia, Eduardo Vitórica-Yrezábal, Iñigo J. Calbo Roig, Joaquín Mínguez Espallargas, Guillermo 2022 Multivariate sodalite zeolitic imidazolate frameworks: a direct solvent-free synthesis Chemical Science 13 3 842 847
https://doi.org/10.1039/D1SC04779E

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