Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolium MOF: Incorporation of POMs and [AuCl4]−
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Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolium MOF: Incorporation of POMs and [AuCl4]−

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Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolium MOF: Incorporation of POMs and [AuCl4]−

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López Cabrelles, Javier; Mínguez Espallargas, Guillermo; Coronado Miralles, Eugenio Perfil
This document is a artículoDate2016
The encapsulation of functional molecules inside porous coordination polymers (also known as metal-organic frameworks, MOFs) has become of great interest in recent years at the field of multifunctional materials. In this article, we present a study of the effects of size and charge in the anion exchange process of a Gd based MOF, involving molecular species like polyoxometalates (POMs), and [AuCl4]−. This post-synthetic modification has been characterized by IR, EDAX, and single crystal diffraction, which have provided unequivocal evidence of the location of the anion molecules in the framework.

    López Cabrelles, Javier Mínguez Espallargas, Guillermo Coronado Miralles, Eugenio 2016 Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolium MOF: Incorporation of POMs and [AuCl4]− Polymers 8 171 1 14
https://doi.org/10.3390/polym8050171

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