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MOF-mediated synthesis of supported Fe-doped Pd nanoparticles under mild conditions for magnetically recoverable catalysis

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MOF-mediated synthesis of supported Fe-doped Pd nanoparticles under mild conditions for magnetically recoverable catalysis

dc.contributor.author	Darawsheh, Mohanad D.
dc.contributor.author	Mazarío, Jaime
dc.contributor.author	Lopes, Christian W.
dc.contributor.author	Giménez Marqués, Mónica
dc.contributor.author	Domine, Marcelo E.
dc.contributor.author	Meira, Debora M.
dc.contributor.author	Martínez, Jordan
dc.contributor.author	Mínguez Espallargas, Guillermo
dc.contributor.author	Oña-Burgos, Pascual
dc.date.accessioned	2021-07-14T17:53:02Z
dc.date.available	2021-07-14T17:53:02Z
dc.date.issued	2020
dc.identifier.uri	https://hdl.handle.net/10550/79934
dc.description.abstract	Metal-organic framework (MOF)-driven synthesis is considered as a promising alternative for the development of new catalytic materials with well-designed active sites. This synthetic approach is used here to gradually transform a new bimetallic MOF, with Pd and Fe as the metal components, by the in situ generation of aniline under mild conditions. This methodology results in a compositionally homogeneous nanocomposite formed by Fe-doped Pd nanoparticles that, in turn, are supported on iron oxide-doped carbon. The nanocomposite has been fully characterized by several techniques such as IR and Raman spectroscopy, TEM, XPS, and XAS. The performance of this nanocomposite as an heterogeneous catalyst for hydrogenation of nitroarenes and nitrobenzene coupling with benzaldehyde has been evaluated, proving it to be an efficient and reusable catalyst.
dc.language.iso	eng
dc.relation.ispartof	Chemistry-A European Journal, 2020, vol. 26, p. 13659-13667
dc.source	Darawsheh, Mohanad D. Mazarío, Jaime Lopes, Christian W. Giménez Marqués, Mónica Domine, Marcelo E. Meira, Debora M. Martínez, Jordan Mínguez Espallargas, Guillermo Oña-Burgos, Pascual 2020 MOF-mediated synthesis of supported Fe-doped Pd nanoparticles under mild conditions for magnetically recoverable catalysis Chemistry-A European Journal 26 13659 13667
dc.subject	Catàlisi
dc.subject	Materials nanoestructurats
dc.title	MOF-mediated synthesis of supported Fe-doped Pd nanoparticles under mild conditions for magnetically recoverable catalysis
dc.type	journal article	es_ES
dc.date.updated	2021-07-14T17:53:03Z
dc.identifier.doi	https://doi.org/10.1002/chem.202001895
dc.identifier.idgrec	141716
dc.rights.accessRights	open access	es_ES