MOF-mediated synthesis of supported Fe-doped Pd nanoparticles under mild conditions for magnetically recoverable catalysis
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MOF-mediated synthesis of supported Fe-doped Pd nanoparticles under mild conditions for magnetically recoverable catalysis

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MOF-mediated synthesis of supported Fe-doped Pd nanoparticles under mild conditions for magnetically recoverable catalysis

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Darawsheh, Mohanad D.; Mazarío, Jaime; Lopes, Christian W.; Giménez Marqués, Mónica; Domine, Marcelo E.; Meira, Debora M.; Martínez, Jordan; Mínguez Espallargas, Guillermo; Oña-Burgos, Pascual
This document is a artículoDate2020
Metal-organic framework (MOF)-driven synthesis is considered as a promising alternative for the development of new catalytic materials with well-designed active sites. This synthetic approach is used here to gradually transform a new bimetallic MOF, with Pd and Fe as the metal components, by the in situ generation of aniline under mild conditions. This methodology results in a compositionally homogeneous nanocomposite formed by Fe-doped Pd nanoparticles that, in turn, are supported on iron oxide-doped carbon. The nanocomposite has been fully characterized by several techniques such as IR and Raman spectroscopy, TEM, XPS, and XAS. The performance of this nanocomposite as an heterogeneous catalyst for hydrogenation of nitroarenes and nitrobenzene coupling with benzaldehyde has been evaluated, proving it to be an efficient and reusable catalyst.

    Darawsheh, Mohanad D. Mazarío, Jaime Lopes, Christian W. Giménez Marqués, Mónica Domine, Marcelo E. Meira, Debora M. Martínez, Jordan Mínguez Espallargas, Guillermo Oña-Burgos, Pascual 2020 MOF-mediated synthesis of supported Fe-doped Pd nanoparticles under mild conditions for magnetically recoverable catalysis Chemistry-A European Journal 26 13659 13667
https://doi.org/10.1002/chem.202001895

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