Influence of interpenetration on the flexibility of MUV-2
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Influence of interpenetration on the flexibility of MUV-2

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Influence of interpenetration on the flexibility of MUV-2

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dc.contributor.author Vicent-Morales, María
dc.contributor.author Vitórica-Yrezábal, Iñigo J.
dc.contributor.author Souto, Manuel
dc.contributor.author Mínguez Espallargas, Guillermo
dc.date.accessioned 2021-07-14T12:42:15Z
dc.date.available 2021-07-14T12:42:15Z
dc.date.issued 2019
dc.identifier.uri https://hdl.handle.net/10550/79930
dc.description.abstract The crystal structure of an interpenetrated tetrathiafulvalene (TTF)-based metal-organic framework (MOF) is reported. This MOF, denoted as MUV-2-i, is the interpenetrated analogue of the hierarchical and flexible MUV-2. Interestingly, the large flexibility exhibited by MUV-2 upon polar solvent adsorption is considerably reduced in the interpenetrated form which can be explained by short S⋯S interactions between adjacent TTF-based ligands ensuring more rigidity in the framework. In addition, the porosity of MUV-2-i is significantly decreased in comparison to that of MUV-2 as shown by the reduced free volume in the crystal structure.
dc.language.iso eng
dc.relation.ispartof Crystengcomm, 2019, vol. 21, p. 3031-3035
dc.rights.uri info:eu-repo/semantics/openAccess
dc.source Vicent-Morales, María Vitórica-Yrezábal, Iñigo J. Souto, Manuel Mínguez Espallargas, Guillermo 2019 Influence of interpenetration on the flexibility of MUV-2 Crystengcomm 21 3031 3035
dc.subject Cristalls
dc.subject Materials
dc.title Influence of interpenetration on the flexibility of MUV-2
dc.type info:eu-repo/semantics/article
dc.date.updated 2021-07-14T12:42:15Z
dc.identifier.doi https://doi.org/10.1039/C9CE00233B
dc.identifier.idgrec 134268

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