Influence of interpenetration on the flexibility of MUV-2
NAGIOS: RODERIC FUNCIONANDO

Influence of interpenetration on the flexibility of MUV-2

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Influence of interpenetration on the flexibility of MUV-2

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Vicent-Morales, María; Vitórica-Yrezábal, Iñigo J.; Souto, Manuel; Mínguez Espallargas, Guillermo
This document is a artículoDate2019
The crystal structure of an interpenetrated tetrathiafulvalene (TTF)-based metal-organic framework (MOF) is reported. This MOF, denoted as MUV-2-i, is the interpenetrated analogue of the hierarchical and flexible MUV-2. Interestingly, the large flexibility exhibited by MUV-2 upon polar solvent adsorption is considerably reduced in the interpenetrated form which can be explained by short S⋯S interactions between adjacent TTF-based ligands ensuring more rigidity in the framework. In addition, the porosity of MUV-2-i is significantly decreased in comparison to that of MUV-2 as shown by the reduced free volume in the crystal structure.

    Vicent-Morales, María Vitórica-Yrezábal, Iñigo J. Souto, Manuel Mínguez Espallargas, Guillermo 2019 Influence of interpenetration on the flexibility of MUV-2 Crystengcomm 21 3031 3035
https://doi.org/10.1039/C9CE00233B

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