Interpenetrated Luminescent Metal-Organic Frameworks based on 1H-Indazole-5-carboxylic Acid
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Interpenetrated Luminescent Metal-Organic Frameworks based on 1H-Indazole-5-carboxylic Acid

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Interpenetrated Luminescent Metal-Organic Frameworks based on 1H-Indazole-5-carboxylic Acid

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García-Valdivia, Antonio A.; Pérez-Mendoza, Manuel; Choquesillo-Lazarte, Duane; Cepeda, Javier; Fernández, Belén; Souto, Manuel; González-Tejero, Marcos; García, J. A.; Mínguez Espallargas, Guillermo; Rodríguez-Diéguez, Antonio
This document is a artículoDate2020
Herein we report the formation and characterization of two novel Zn-based multifunctional metal-organic frameworks (MOFs) based on 1H-indazole-5-carboxylic acid and bipyridine-like linkers, synthesized by soft solvothermal routes. These materials possess isoreticular 2-fold interpenetrated three-dimensional structures that afford a flexible character and allow porosity modulation of the MOFs as confirmed by CO2 sorption measurements. Apart from this attractive structural feature, the MOFs exhibit fascinating luminescent properties involving both luminescence thermometry and long-lasting phosphorescence.

    García-Valdivia, Antonio A. Pérez-Mendoza, Manuel Choquesillo-Lazarte, Duane Cepeda, Javier Fernández, Belén Souto, Manuel González-Tejero, Marcos García, J. A. Mínguez Espallargas, Guillermo Rodríguez-Diéguez, Antonio 2020 Interpenetrated Luminescent Metal-Organic Frameworks based on 1H-Indazole-5-carboxylic Acid Crystal Growth & Design 20 7 4550 4560
https://doi.org/10.1021/acs.cgd.0c00345

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