Electronic, Structural and Functional Versatility in Tetrathiafulvalene-Lanthanide Metal-Organic Frameworks
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Electronic, Structural and Functional Versatility in Tetrathiafulvalene-Lanthanide Metal-Organic Frameworks

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Electronic, Structural and Functional Versatility in Tetrathiafulvalene-Lanthanide Metal-Organic Frameworks

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dc.contributor.author Castells-Gil, Javier
dc.contributor.author Mañas Valero, Samuel
dc.contributor.author Vitórica-Yrezábal, Iñigo J.
dc.contributor.author Ananias, Duarte
dc.contributor.author Rocha, João
dc.contributor.author Santiago, Raúl
dc.contributor.author Bromley, Stefan T.
dc.contributor.author Baldoví, José J.
dc.contributor.author Coronado Miralles, Eugenio
dc.contributor.author Souto, Manuel
dc.contributor.author Mínguez Espallargas, Guillermo
dc.date.accessioned 2021-07-13T14:42:46Z
dc.date.available 2021-07-13T14:42:46Z
dc.date.issued 2019
dc.identifier.uri https://hdl.handle.net/10550/79915
dc.description.abstract Tetrathiafulvalene-lanthanide (TTF-Ln) metal-organic frameworks (MOFs) are an interesting class of multifunctional materials in which porosity can be combined with electronic properties such as electrical conductivity, redox activity, luminescence and magnetism. Herein a new family of isostructural TTF-Ln MOFs is reported, denoted as MUV-5(Ln) (Ln=Gd, Tb, Dy, Ho, Er), exhibiting semiconducting properties as a consequence of the short intermolecular S⋅⋅⋅S contacts established along the chain direction between partially oxidised TTF moieties. In addition, this family shows photoluminescence properties and single-molecule magnetic behaviour, finding near-infrared (NIR) photoluminescence in the Yb/Er derivative and slow relaxation of the magnetisation in the Dy and Er derivatives. As such properties are dependent on the electronic structure of the lanthanide ion, the immense structural, electronic and functional versatility of this class of materials is emphasised.
dc.language.iso eng
dc.relation.ispartof Chemistry-A European Journal, 2019, vol. 25, p. 12636 -12643
dc.rights.uri info:eu-repo/semantics/openAccess
dc.source Castells-Gil, Javier Mañas Valero, Samuel Vitórica-Yrezábal, Iñigo J. Ananias, Duarte Rocha, João Santiago, Raúl Bromley, Stefan T. Baldoví, José J. Coronado Miralles, Eugenio Souto, Manuel Mínguez Espallargas, Guillermo 2019 Electronic, Structural and Functional Versatility in Tetrathiafulvalene-Lanthanide Metal-Organic Frameworks Chemistry-A European Journal 25 12636 12643
dc.subject Materials
dc.subject Conductivitat elèctrica
dc.title Electronic, Structural and Functional Versatility in Tetrathiafulvalene-Lanthanide Metal-Organic Frameworks
dc.type info:eu-repo/semantics/article
dc.date.updated 2021-07-13T14:42:46Z
dc.identifier.doi https://doi.org/10.1002/chem.201902855
dc.identifier.idgrec 136738

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