Charge-transfer interactions between fullerenes and a mesoporous tetrathiafulvalene-based metal-organic framework
NAGIOS: RODERIC FUNCIONANDO

Charge-transfer interactions between fullerenes and a mesoporous tetrathiafulvalene-based metal-organic framework

DSpace Repository

Charge-transfer interactions between fullerenes and a mesoporous tetrathiafulvalene-based metal-organic framework

Show simple item record

dc.contributor.author Souto, Manuel
dc.contributor.author Calbo Roig, Joaquín
dc.contributor.author Mañas Valero, Samuel
dc.contributor.author Walsh, Aron
dc.contributor.author Mínguez Espallargas, Guillermo
dc.date.accessioned 2021-07-13T13:47:44Z
dc.date.available 2021-07-13T13:47:44Z
dc.date.issued 2019
dc.identifier.uri https://hdl.handle.net/10550/79914
dc.description.abstract The design of metal-organic frameworks (MOFs) incorporating electroactive guest molecules in the pores has become a subject of great interest in order to obtain additional electrical functionalities within the framework while maintaining porosity. Understanding the charge-transfer (CT) process between the framework and the guest molecules is a crucial step towards the design of new electroactive MOFs. Herein, we present the encapsulation of fullerenes (C60) in a mesoporous tetrathiafulvalene (TTF)-based MOF. The CT process between the electron-acceptor C60 guest and the electron-donor TTF ligand is studied in detail by means of different spectroscopic techniques and density functional theory (DFT) calculations. Importantly, gas sorption measurements demonstrate that sorption capacity is maintained after encapsulation of fullerenes, whereas the electrical conductivity is increased by two orders of magnitude due to the CT interactions between C60 and the TTF-based framework.
dc.language.iso eng
dc.relation.ispartof Beilstein Journal Of Nanotechnology, 2019, vol. 10, p. 1883-1893
dc.rights.uri info:eu-repo/semantics/openAccess
dc.source Souto, Manuel Calbo Roig, Joaquín Mañas Valero, Samuel Walsh, Aron Mínguez Espallargas, Guillermo 2019 Charge-transfer interactions between fullerenes and a mesoporous tetrathiafulvalene-based metal-organic framework Beilstein Journal Of Nanotechnology 10 1883 1893
dc.subject Materials
dc.subject Nanotecnologia
dc.title Charge-transfer interactions between fullerenes and a mesoporous tetrathiafulvalene-based metal-organic framework
dc.type info:eu-repo/semantics/article
dc.date.updated 2021-07-13T13:47:45Z
dc.identifier.doi https://doi.org/10.3762/bjnano.10.183
dc.identifier.idgrec 134271

View       (3.381Mb)

This item appears in the following Collection(s)

Show simple item record

Search DSpace

Advanced Search

Browse

Statistics