dc.contributor.author |
Tejeda-Serrano, María |
|
dc.contributor.author |
Lloret, Vicent |
|
dc.contributor.author |
Márkus, Bence G. |
|
dc.contributor.author |
Simon, Ferenc |
|
dc.contributor.author |
Hauke, Frank |
|
dc.contributor.author |
Hirsch, Andreas |
|
dc.contributor.author |
Doménech Carbó, Antonio |
|
dc.contributor.author |
Abellán Sáez, Gonzalo |
|
dc.contributor.author |
Leyva-Pérez, Antonio |
|
dc.date.accessioned |
2021-05-24T13:56:56Z |
|
dc.date.available |
2021-05-24T13:56:56Z |
|
dc.date.issued |
2020 |
|
dc.identifier.uri |
https://hdl.handle.net/10550/79381 |
|
dc.description.abstract |
The substitution of catalytic metals by p-block main elements has a tremendous impact not only in the fundamentals but also in the economic and ecological fingerprint of organic reactions. Here we show that few-layer black phosphorous (FL-BP), a recently discovered and now readily available 2D material, catalyzes different radical additions to alkenes with an initial turnover frequency (TOF0) up to two orders of magnitude higher than representative state-of-the-art metal complex catalysts at room temperature. The corresponding electron-rich BP intercalation compound (BPIC) KP6 shows a nearly twice TOF0 increase with respect to FL-BP. This increase in catalytic activity respect to the neutral counterpart also occurs in other 2D materials (graphene vs. KC8) and metal complex catalysts (Fe0 vs. Fe2− carbon monoxide complexes). This reactive parallelism opens the door for cross-fertilization between 2D materials and metal catalysts in organic synthesis. |
|
dc.language.iso |
eng |
|
dc.relation.ispartof |
Chemcatchem, 2020, vol. 12, num. 8, p. 2226-2232 |
|
dc.rights.uri |
info:eu-repo/semantics/openAccess |
|
dc.source |
Tejeda-Serrano, María Lloret, Vicent Márkus, Bence G. Simon, Ferenc Hauke, Frank Hirsch, Andreas Doménech Carbó, Antonio Abellán Sáez, Gonzalo Leyva-Pérez, Antonio 2020 Few-layer Black Phosphorous Catalyzes Radical Additions to Alkenes Faster than Low-valence Metals Chemcatchem 12 8 2226 2232 |
|
dc.subject |
Materials |
|
dc.subject |
Catàlisi |
|
dc.title |
Few-layer Black Phosphorous Catalyzes Radical Additions to Alkenes Faster than Low-valence Metals |
|
dc.type |
info:eu-repo/semantics/article |
|
dc.date.updated |
2021-05-24T13:56:57Z |
|
dc.identifier.doi |
https://doi.org/10.1002/cctc.201902276 |
|
dc.identifier.idgrec |
144557 |
|