Few-layer Black Phosphorous Catalyzes Radical Additions to Alkenes Faster than Low-valence Metals
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Few-layer Black Phosphorous Catalyzes Radical Additions to Alkenes Faster than Low-valence Metals

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Few-layer Black Phosphorous Catalyzes Radical Additions to Alkenes Faster than Low-valence Metals

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dc.contributor.author Tejeda-Serrano, María
dc.contributor.author Lloret, Vicent
dc.contributor.author Márkus, Bence G.
dc.contributor.author Simon, Ferenc
dc.contributor.author Hauke, Frank
dc.contributor.author Hirsch, Andreas
dc.contributor.author Doménech Carbó, Antonio
dc.contributor.author Abellán Sáez, Gonzalo
dc.contributor.author Leyva-Pérez, Antonio
dc.date.accessioned 2021-05-24T13:56:56Z
dc.date.available 2021-05-24T13:56:56Z
dc.date.issued 2020
dc.identifier.uri https://hdl.handle.net/10550/79381
dc.description.abstract The substitution of catalytic metals by p-block main elements has a tremendous impact not only in the fundamentals but also in the economic and ecological fingerprint of organic reactions. Here we show that few-layer black phosphorous (FL-BP), a recently discovered and now readily available 2D material, catalyzes different radical additions to alkenes with an initial turnover frequency (TOF0) up to two orders of magnitude higher than representative state-of-the-art metal complex catalysts at room temperature. The corresponding electron-rich BP intercalation compound (BPIC) KP6 shows a nearly twice TOF0 increase with respect to FL-BP. This increase in catalytic activity respect to the neutral counterpart also occurs in other 2D materials (graphene vs. KC8) and metal complex catalysts (Fe0 vs. Fe2− carbon monoxide complexes). This reactive parallelism opens the door for cross-fertilization between 2D materials and metal catalysts in organic synthesis.
dc.language.iso eng
dc.relation.ispartof Chemcatchem, 2020, vol. 12, num. 8, p. 2226-2232
dc.rights.uri info:eu-repo/semantics/openAccess
dc.source Tejeda-Serrano, María Lloret, Vicent Márkus, Bence G. Simon, Ferenc Hauke, Frank Hirsch, Andreas Doménech Carbó, Antonio Abellán Sáez, Gonzalo Leyva-Pérez, Antonio 2020 Few-layer Black Phosphorous Catalyzes Radical Additions to Alkenes Faster than Low-valence Metals Chemcatchem 12 8 2226 2232
dc.subject Materials
dc.subject Catàlisi
dc.title Few-layer Black Phosphorous Catalyzes Radical Additions to Alkenes Faster than Low-valence Metals
dc.type info:eu-repo/semantics/article
dc.date.updated 2021-05-24T13:56:57Z
dc.identifier.doi https://doi.org/10.1002/cctc.201902276
dc.identifier.idgrec 144557

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