Insertion of single-ion magnets based on mononuclear Co(II) complexes into ferromagnetic oxalate-based networks
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Insertion of single-ion magnets based on mononuclear Co(II) complexes into ferromagnetic oxalate-based networks

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Insertion of single-ion magnets based on mononuclear Co(II) complexes into ferromagnetic oxalate-based networks

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dc.contributor.author Palacios-Corella, M.
dc.contributor.author García López, Víctor
dc.contributor.author Sánchez-Sánchez, C.
dc.contributor.author Clemente Juan, Juan Modesto
dc.contributor.author Clemente León, Miguel
dc.contributor.author Coronado Miralles, Eugenio
dc.date.accessioned 2021-04-21T15:00:19Z
dc.date.available 2021-04-21T15:00:19Z
dc.date.issued 2021
dc.identifier.uri https://hdl.handle.net/10550/78872
dc.description.abstract The 1 : 2 and 1 : 1 Co(II) complexes of the L ligand (L = 6-(3,5-diamino-2,4,6-triazinyl)2,2′-bipyridine) with formulas [CoII(L)2](ClO4)2·0.5MeCN·Et2O (1) and [CoII(L)(CH3CN)2(H2O)](ClO4)2·MeCN (2) have been prepared. The structural and magnetic characterization of the two compounds shows that they contain octahedral high-spin Co(II) and present a field-induced slow relaxation of the magnetization. 1 has been inserted into a bimetallic oxalate-based network leading to a novel achiral 3D compound of formula [CoII(L)2][MnIICrIII(ox)3]2·(solvate) (3) exhibiting ferromagnetic ordering below 4.6 K. EPR measurements suggest a weak magnetic coupling between the two sublattices.
dc.language.iso eng
dc.relation.ispartof Dalton Transactions, 2021
dc.rights.uri info:eu-repo/semantics/openAccess
dc.source Palacios-Corella, M. García López, Víctor Sánchez-Sánchez, C. Clemente Juan, Juan Modesto Clemente León, Miguel Coronado Miralles, Eugenio 2021 Insertion of single-ion magnets based on mononuclear Co(II) complexes into ferromagnetic oxalate-based networks Dalton Transactions
dc.subject Química organometàl·lica
dc.title Insertion of single-ion magnets based on mononuclear Co(II) complexes into ferromagnetic oxalate-based networks
dc.type info:eu-repo/semantics/article
dc.date.updated 2021-04-21T15:00:19Z
dc.identifier.doi https://doi.org/10.1039/D1DT00595B
dc.identifier.idgrec 145215
dc.embargo.terms 1 year
dc.embargo.liftdate 2022-03-23

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