Insertion of single-ion magnets based on mononuclear Co(II) complexes into ferromagnetic oxalate-based networks
NAGIOS: RODERIC FUNCIONANDO

Insertion of single-ion magnets based on mononuclear Co(II) complexes into ferromagnetic oxalate-based networks

DSpace Repository

Insertion of single-ion magnets based on mononuclear Co(II) complexes into ferromagnetic oxalate-based networks

Show full item record

View       (4.675Mb)

Exportar a Refworks
    
Palacios-Corella, M.; García López, Víctor; Sánchez-Sánchez, C.; Clemente Juan, Juan Modesto; Clemente León, Miguel; Coronado Miralles, Eugenio Perfil
This document is a artículoDate2021
The 1 : 2 and 1 : 1 Co(II) complexes of the L ligand (L = 6-(3,5-diamino-2,4,6-triazinyl)2,2′-bipyridine) with formulas [CoII(L)2](ClO4)2·0.5MeCN·Et2O (1) and [CoII(L)(CH3CN)2(H2O)](ClO4)2·MeCN (2) have been prepared. The structural and magnetic characterization of the two compounds shows that they contain octahedral high-spin Co(II) and present a field-induced slow relaxation of the magnetization. 1 has been inserted into a bimetallic oxalate-based network leading to a novel achiral 3D compound of formula [CoII(L)2][MnIICrIII(ox)3]2·(solvate) (3) exhibiting ferromagnetic ordering below 4.6 K. EPR measurements suggest a weak magnetic coupling between the two sublattices.

    Palacios-Corella, M. García López, Víctor Sánchez-Sánchez, C. Clemente Juan, Juan Modesto Clemente León, Miguel Coronado Miralles, Eugenio 2021 Insertion of single-ion magnets based on mononuclear Co(II) complexes into ferromagnetic oxalate-based networks Dalton Transactions
https://doi.org/10.1039/D1DT00595B

This item appears in the following Collection(s)

Show full item record

Search DSpace

Advanced Search

Browse

Statistics