dc.contributor.author |
Gil-San-Millan, Rodrigo |
|
dc.contributor.author |
López Maya, Elena |
|
dc.contributor.author |
́Platero-Prats, Ana E. |
|
dc.contributor.author |
Torres-Pérez, Virginia |
|
dc.contributor.author |
Delgado, Pedro |
|
dc.contributor.author |
́Augustyniak, Adam W. |
|
dc.contributor.author |
Kim, Min Kun |
|
dc.contributor.author |
Lee, Hae Wan |
|
dc.contributor.author |
Ryu, Sam Gon |
|
dc.contributor.author |
Navarro, Jorge A. R. |
|
dc.date.accessioned |
2020-07-24T10:20:24Z |
|
dc.date.available |
2020-07-24T10:20:24Z |
|
dc.date.issued |
2019 |
|
dc.identifier.uri |
https://hdl.handle.net/10550/75353 |
|
dc.description.abstract |
UiO-66, MOF-808 and NU-1000 metal-organic frameworks exhibit a differentiated reactivity toward [Mg(OMe)2(MeOH)2]4 related to their pore accessibility. Microporous UiO-66 remains unchanged while mesoporous MOF-808 and hierarchical micro/mesoporous NU-1000 materials yield doped systems containing exposed MgZr5O2(OH)6 clusters in the mesoporous cavities. This modification is responsible for a remarkable enhancement of the catalytic activity toward the hydrolytic degradation of P-F and P-S bonds of toxic nerve agents, at room temperature, in unbuffered aqueous solutions. |
|
dc.language.iso |
eng |
|
dc.relation.ispartof |
Journal of the American Chemical Society, 2019, vol. 141, num. 30, p. 11801-11805 |
|
dc.rights.uri |
info:eu-repo/semantics/openAccess |
|
dc.source |
Gil-San-Millan, Rodrigo López Maya, Elena ́Platero-Prats, Ana E. Torres-Pérez, Virginia Delgado, Pedro ́Augustyniak, Adam W. Kim, Min Kun Lee, Hae Wan Ryu, Sam Gon Navarro, Jorge A. R. 2019 Magnesium Exchanged Zirconium Metal−Organic Frameworks with Improved Detoxification Properties of Nerve Agents Journal of the American Chemical Society 141 30 11801 11805 |
|
dc.subject |
Química organometàl·lica |
|
dc.subject |
Materials |
|
dc.title |
Magnesium Exchanged Zirconium Metal−Organic Frameworks with Improved Detoxification Properties of Nerve Agents |
|
dc.type |
info:eu-repo/semantics/article |
|
dc.date.updated |
2020-07-24T10:20:25Z |
|
dc.identifier.doi |
https://doi.org/10.1021/jacs.9b05571 |
|
dc.identifier.idgrec |
138024 |
|