Magnesium Exchanged Zirconium Metal−Organic Frameworks with Improved Detoxification Properties of Nerve Agents
NAGIOS: RODERIC FUNCIONANDO

Magnesium Exchanged Zirconium Metal−Organic Frameworks with Improved Detoxification Properties of Nerve Agents

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Magnesium Exchanged Zirconium Metal−Organic Frameworks with Improved Detoxification Properties of Nerve Agents

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dc.contributor.author Gil-San-Millan, Rodrigo
dc.contributor.author López Maya, Elena
dc.contributor.author ́Platero-Prats, Ana E.
dc.contributor.author Torres-Pérez, Virginia
dc.contributor.author Delgado, Pedro
dc.contributor.author ́Augustyniak, Adam W.
dc.contributor.author Kim, Min Kun
dc.contributor.author Lee, Hae Wan
dc.contributor.author Ryu, Sam Gon
dc.contributor.author Navarro, Jorge A. R.
dc.date.accessioned 2020-07-24T10:20:24Z
dc.date.available 2020-07-24T10:20:24Z
dc.date.issued 2019
dc.identifier.uri https://hdl.handle.net/10550/75353
dc.description.abstract UiO-66, MOF-808 and NU-1000 metal-organic frameworks exhibit a differentiated reactivity toward [Mg(OMe)2(MeOH)2]4 related to their pore accessibility. Microporous UiO-66 remains unchanged while mesoporous MOF-808 and hierarchical micro/mesoporous NU-1000 materials yield doped systems containing exposed MgZr5O2(OH)6 clusters in the mesoporous cavities. This modification is responsible for a remarkable enhancement of the catalytic activity toward the hydrolytic degradation of P-F and P-S bonds of toxic nerve agents, at room temperature, in unbuffered aqueous solutions.
dc.language.iso eng
dc.relation.ispartof Journal of the American Chemical Society, 2019, vol. 141, num. 30, p. 11801-11805
dc.rights.uri info:eu-repo/semantics/openAccess
dc.source Gil-San-Millan, Rodrigo López Maya, Elena &#769Platero-Prats, Ana E. Torres-Pérez, Virginia Delgado, Pedro &#769Augustyniak, Adam W. Kim, Min Kun Lee, Hae Wan Ryu, Sam Gon Navarro, Jorge A. R. 2019 Magnesium Exchanged Zirconium Metal−Organic Frameworks with Improved Detoxification Properties of Nerve Agents Journal of the American Chemical Society 141 30 11801 11805
dc.subject Química organometàl·lica
dc.subject Materials
dc.title Magnesium Exchanged Zirconium Metal−Organic Frameworks with Improved Detoxification Properties of Nerve Agents
dc.type info:eu-repo/semantics/article
dc.date.updated 2020-07-24T10:20:25Z
dc.identifier.doi https://doi.org/10.1021/jacs.9b05571
dc.identifier.idgrec 138024

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