A Straightforward approach to multifunctional graphene
NAGIOS: RODERIC FUNCIONANDO

A Straightforward approach to multifunctional graphene

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A Straightforward approach to multifunctional graphene

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dc.contributor.author Lucherelli, Matteo Andrea
dc.contributor.author Raya, Jésus
dc.contributor.author Edelthalhammer, Konstantin F.
dc.contributor.author Hauke, Frank
dc.contributor.author Hirsch, Andreas
dc.contributor.author Abellán Sáez, Gonzalo
dc.contributor.author Bianco, Alberto
dc.date.accessioned 2020-05-11T09:20:55Z
dc.date.available 2020-09-11T04:45:05Z
dc.date.issued 2019
dc.identifier.uri https://hdl.handle.net/10550/74556
dc.description.abstract Graphene has been covalently functionalized through a one‐pot reductive pathway using graphite intercalation compounds (GICs), in particular KC8, with three different orthogonally protected derivatives of 4‐aminobenzylamine. This novel multifunctional platform exhibits excellent bulk functionalization homogeneity (Hbulk) and degree of addition while preserving the chemical functionalities of the organic addends through different protecting groups, namely: tert‐butyloxycarbonyl (Boc), benzyloxycarbonyl (Cbz) and phthalimide (Pht). We have employed (temperature‐dependent) statistical Raman spectroscopy (SRS), X‐ray photoelectron spectroscopy (XPS), magic angle spinning solid state 13C NMR (MAS‐NMR), and a characterization tool consisting of thermogravimetric analysis coupled with gas chromatography and mass spectrometry (TG‐GC‐MS) to unambiguously demonstrate the covalent binding and the chemical nature of the different molecular linkers. This work paves the way for the development of smart graphene‐based materials of great interest in biomedicine or electronics, to name a few, and will serve as a guide in the design of new 2D multifunctional materials.
dc.language.iso eng
dc.relation.ispartof Chemistry-A European Journal, 2019, vol. 25, num. 57, p. 13218-13223
dc.rights.uri info:eu-repo/semantics/openAccess
dc.source Lucherelli, Matteo Andrea Raya, Jésus Edelthalhammer, Konstantin F. Hauke, Frank Hirsch, Andreas Abellán Sáez, Gonzalo Bianco, Alberto 2019 A Straightforward approach to multifunctional graphene Chemistry-A European Journal 25 57 13218 13223
dc.subject Materials
dc.subject Compostos orgànics
dc.title A Straightforward approach to multifunctional graphene
dc.type info:eu-repo/semantics/article
dc.date.updated 2020-05-11T09:20:55Z
dc.identifier.doi https://doi.org/10.1002/chem.201903165
dc.identifier.idgrec 138862
dc.embargo.terms 1 year

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