Few layer 2D pnictogens (P & Sb) catalyze the alkylation of soft nucleophiles with esters
NAGIOS: RODERIC FUNCIONANDO

Few layer 2D pnictogens (P & Sb) catalyze the alkylation of soft nucleophiles with esters

DSpace Repository

Few layer 2D pnictogens (P & Sb) catalyze the alkylation of soft nucleophiles with esters

Show simple item record

dc.contributor.author Lloret, Vicent
dc.contributor.author Rivero‐Crespo, Miguel Ángel
dc.contributor.author Vidal-Moya, Alejandro
dc.contributor.author Wild, Stefan
dc.contributor.author Doménech Carbó, Antonio
dc.contributor.author Heller, Bettina S. J.
dc.contributor.author Shin, Sunghwan
dc.contributor.author Steinrück, Peter
dc.contributor.author Maier, Florian
dc.contributor.author Hauke, Frank
dc.contributor.author Varela, Maria
dc.contributor.author Hirsch, Andreas
dc.contributor.author Leyva-Pérez, Antonio
dc.contributor.author Abellán Sáez, Gonzalo
dc.date.accessioned 2020-05-08T08:52:43Z
dc.date.available 2020-05-08T08:52:43Z
dc.date.issued 2019
dc.identifier.uri https://hdl.handle.net/10550/74540
dc.description.abstract Group 15 elements in zero oxidation state (P, As, Sb and Bi), also called pnictogens, are rarely used in catalysis due to the difficulties associated in preparing well-structured and stable materials. Here, we report on the synthesis of highly exfoliated, few layer 2D phosphorene and antimonene in zero oxidation state, suspended in an ionic liquid, with the native atoms ready to interact with external reagents while avoiding aerobic or aqueous decomposition pathways, and on their use as efficient catalysts for the alkylation of nucleophiles with esters. The few layer pnictogen material circumvents the extremely harsh reaction conditions associated to previous superacid-catalyzed alkylations, by enabling an alternative mechanism on surface, protected from the water and air by the ionic liquid. These 2D catalysts allow the alkylation of a variety of acid-sensitive organic molecules and giving synthetic relevancy to the use of simple esters as alkylating agents.
dc.language.iso eng
dc.relation.ispartof Nature Communications, 2019, vol. 10, num. 509
dc.rights.uri info:eu-repo/semantics/openAccess
dc.source Lloret, Vicent Rivero&#8208Crespo, Miguel Ángel Vidal-Moya, Alejandro Wild, Stefan Doménech Carbó, Antonio Heller, Bettina S. J. Shin, Sunghwan Steinrück, Peter Maier, Florian Hauke, Frank Varela, Maria Hirsch, Andreas Leyva-Pérez, Antonio Abellán Sáez, Gonzalo 2019 Few layer 2D pnictogens (P & Sb) catalyze the alkylation of soft nucleophiles with esters Nature Communications 10 509
dc.subject Materials
dc.subject Catàlisi heterogènia
dc.title Few layer 2D pnictogens (P & Sb) catalyze the alkylation of soft nucleophiles with esters
dc.type info:eu-repo/semantics/article
dc.date.updated 2020-05-08T08:52:43Z
dc.identifier.doi https://doi.org/10.1038/s41467-018-08063-3
dc.identifier.idgrec 136942

View       (2.069Mb)

This item appears in the following Collection(s)

Show simple item record

Search DSpace

Advanced Search

Browse

Statistics