Organocatalytic enantioselective Strecker reaction with seven-membered cyclic imines
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Organocatalytic enantioselective Strecker reaction with seven-membered cyclic imines

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Organocatalytic enantioselective Strecker reaction with seven-membered cyclic imines

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Lluna-Galán, Carles; Blay Llinares, Gonzalo Perfil; Fernández Picot, Isabel; Muñoz, M. Carmen; Pedro, José Ramón; Vila Descals, Carlos
This document is a artículoDate2018
A highly enantioselective Strecker reaction with dibenzo[b,f][1,4]oxazepines has been described using a dihydroquinine-derived thiourea as organocatalyst. The reaction affords chiral 10,11-dihydrodibenzo[b,f][1,4]oxazepine 11-carbonitrile derivatives in excellent yields (up to 99%) and excellent enantioselectivities (up to 98%) under mild reaction conditions.

    Lluna-Galán, Carles Blay Llinares, Gonzalo Fernández Picot, Isabel Muñoz, M. Carmen Pedro, José Ramón Vila Descals, Carlos 2018 Organocatalytic enantioselective Strecker reaction with seven-membered cyclic imines Advanced Synthesis & Catalysis 360 19 3662 3666
https://doi.org/10.1002/adsc.201800754

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