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Enantioselective alkynylation of benzo[e][1,2,3]-oxathiazine 2,2-dioxides catalysed by (R)-VAPOL-Zn complexes: synthesis of chiral propargylic cyclic sulfamidates
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Enantioselective alkynylation of benzo[e][1,2,3]-oxathiazine 2,2-dioxides catalysed by (R)-VAPOL-Zn complexes: synthesis of chiral propargylic cyclic sulfamidates
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| De Munck, Lode; Monleón Ventura, Alicia; Vila Descals, Carlos; Muñoz, M. Carmen; Pedro, José Ramón | |
| This document is a artículoDate2015 | |
| (R)-VAPOL-Zn(II) complexes catalysed the enantioselective addition of terminal alkynes to cyclic benzoxathiazine 2,2-dioxides, providing the corresponding chiral propargylic sulfamidates with high yields (up to 93%) and good enantiomeric excesses (up to 87%). | |
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De Munck, Lode Monleón Ventura, Alicia Vila Descals, Carlos Muñoz, M. Carmen Pedro, José Ramón 2015 Enantioselective alkynylation of benzo[e][1,2,3]-oxathiazine 2,2-dioxides catalysed by (R)-VAPOL-Zn complexes: synthesis of chiral propargylic cyclic sulfamidates Organic & Biomolecular Chemistry 13 27 7393 7396 |
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| https://doi.org/10.1039/C5OB01012H |
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