Organocatalytic enantioselective functionalization of indoles in the carbocyclic ring with cyclic imines
NAGIOS: RODERIC FUNCIONANDO

Organocatalytic enantioselective functionalization of indoles in the carbocyclic ring with cyclic imines

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Organocatalytic enantioselective functionalization of indoles in the carbocyclic ring with cyclic imines

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Vila Descals, Carlos; Tortosa, Arturo; Blay Llinares, Gonzalo Perfil; Muñoz, M. Carmen; Pedro, José Ramón
This document is a artículoDate2019
An organocatalytic enantioselective functionalization in the carbocyclic ring of indoles with benzoxathiazine 2,2-dioxides is described using a quinine-derived bifunctional organocatalyst. This aza-Friedel-Crafts reaction provides 4-indolyl, 5-indolyl and 7-indolyl sulfamidate derivatives in good yields (up to 99%) and with moderate to high enantioselectivities (up to 86% ee).

    Vila Descals, Carlos Tortosa, Arturo Blay Llinares, Gonzalo Muñoz, M. Carmen Pedro, José Ramón 2019 Organocatalytic enantioselective functionalization of indoles in the carbocyclic ring with cyclic imines New Journal of Chemistry 43 1 130 134
https://doi.org/10.1039/C8NJ05577G

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