Self-assembly of catalytically-active supramolecular coordination compounds within metal-organic frameworks
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Self-assembly of catalytically-active supramolecular coordination compounds within metal-organic frameworks

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Self-assembly of catalytically-active supramolecular coordination compounds within metal-organic frameworks

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dc.contributor.author Adam Ortiz, Rosa
dc.contributor.author Mon Conejero, Marta
dc.contributor.author Greco, Rossella
dc.contributor.author Kalinke, Lucas H. G.
dc.contributor.author Vidal-Moya, Alejandro
dc.contributor.author Fernandez, Antonio
dc.contributor.author Winpenny, Richard E. P.
dc.contributor.author Doménech Carbó, Antonio
dc.contributor.author Leyva-Pérez, Antonio
dc.contributor.author Armentano, Donatella
dc.contributor.author Pardo Marín, Emilio
dc.contributor.author Ferrando Soria, Jesús
dc.date.accessioned 2019-07-23T08:17:08Z
dc.date.available 2020-06-13T04:45:05Z
dc.date.issued 2019
dc.identifier.uri https://hdl.handle.net/10550/70986
dc.description.abstract Supramolecular Coordination Compounds (SCCs) represent the power of Coordination Chemistry methodologies to self-assemble discrete architectures with targeted properties. SCCs are generally synthesised in solution, with isolated fully-coordinated metal atoms as structural nodes, thus severely limited as metal-based catalysts. Metal-Organic Frameworks (MOFs) show unique features to act as chemical nanoreactors for the in-situ synthesis and stabilization of otherwise not accessible functional species. Here, we present the self-assembly of PdII SCCs within the confined space of a preformed MOF (SCCs@MOF) and its post-assembly metalation to give a PdII-AuIII supramolecular assembly, crystallography underpinned. These SCCs@MOF catalyse the coupling of boronic acids and/or alkynes, representative multisite metallic-catalysed reactions in which traditional SCCs tend to decompose, and retain its structural integrity as consequence of the synergetic hybridization between SCCs and MOF. These results open new avenues in both the synthesis of novel SCCs and their use on heterogeneous metal-based Supramolecular Catalysis.
dc.language.iso eng
dc.relation.ispartof Journal of the American Chemical Society, 2019, vol. 141, num. 26, p. 10350-10360
dc.rights.uri info:eu-repo/semantics/openAccess
dc.source Adam Ortiz, Rosa Mon Conejero, Marta Greco, Rossella Kalinke, Lucas H. G. Vidal-Moya, Alejandro Fernandez, Antonio Winpenny, Richard E. P. Doménech Carbó, Antonio Leyva-Pérez, Antonio Armentano, Donatella Pardo Marín, Emilio Ferrando Soria, Jesús 2019 Self-Assembly of Catalytically-Active Supramolecular Coordination Compounds within Metal-Organic Frameworks Journal of the American Chemical Society 141 26 10350 10360
dc.subject Química organometàl·lica
dc.title Self-assembly of catalytically-active supramolecular coordination compounds within metal-organic frameworks
dc.type info:eu-repo/semantics/article
dc.date.updated 2019-07-23T08:17:09Z
dc.identifier.doi https://doi.org/10.1021/jacs.9b03914
dc.identifier.idgrec 133390
dc.embargo.terms 1 year

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