Direct visualization of pyrrole reactivity by confined oxidation in a Cyclodextrin Metal‐Organic Framework
NAGIOS: RODERIC FUNCIONANDO

Direct visualization of pyrrole reactivity by confined oxidation in a Cyclodextrin Metal‐Organic Framework

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Direct visualization of pyrrole reactivity by confined oxidation in a Cyclodextrin Metal‐Organic Framework

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dc.contributor.author Núñez-López, Alejandro
dc.contributor.author Galbiati, Marta
dc.contributor.author Padial, Natalia M.
dc.contributor.author Ganivet, Carolina R.
dc.contributor.author Tatay Aguilar, Sergio
dc.contributor.author Pardo Marín, Emilio
dc.contributor.author Armentano, Donatella
dc.contributor.author Martí Gastaldo, Carlos
dc.date.accessioned 2019-07-08T12:58:28Z
dc.date.available 2019-07-10T04:45:05Z
dc.date.issued 2019
dc.identifier.uri https://hdl.handle.net/10550/70758
dc.description.abstract Metal-organic frameworks can be used as porous templates to exert control over polymerization reactions. Shown here are the possibilities offered by these crystalline, porous nanoreactors to capture highly‐reactive intermediates for a better understanding of the mechanism of polymerization reactions. By using a cyclodextrin framework the polymerization of pyrrole is restricted, capturing the formation of terpyrrole cationic intermediates. Single‐crystal X‐ray diffraction is used to provide definite information on the supramolecular interactions that induce the formation and stabilization of a conductive array of cationic complexes.
dc.language.iso eng
dc.relation.ispartof Angewandte Chemie, 2019, vol. 58, num. 27, p. 9179-9183
dc.rights.uri info:eu-repo/semantics/openAccess
dc.source Núñez-López, Alejandro Galbiati, Marta Padial, Natalia M. Ganivet, Carolina R. Tatay Aguilar, Sergio Pardo Marín, Emilio Armentano, Donatella Martí Gastaldo, Carlos 2019 Direct visualization of pyrrole reactivity by confined oxidation in a Cyclodextrin Metal‐Organic Framework Angewandte Chemie 58 27 9179 9183
dc.subject Química organometàl·lica
dc.subject Reactivitat (Química)
dc.title Direct visualization of pyrrole reactivity by confined oxidation in a Cyclodextrin Metal‐Organic Framework
dc.type info:eu-repo/semantics/article
dc.date.updated 2019-07-08T12:58:28Z
dc.identifier.doi https://doi.org/10.1002/anie.201904890
dc.identifier.idgrec 133389
dc.embargo.terms 1 year

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