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Bottom‐Up Fabrication of Semiconductive Metal-Organic Framework Ultrathin Films

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Bottom‐Up Fabrication of Semiconductive Metal-Organic Framework Ultrathin Films

dc.contributor.author	Rubio-Giménez, Víctor
dc.contributor.author	Galbiati, Marta
dc.contributor.author	Castells-Gil, Javier
dc.contributor.author	Almora-Barrios, Neyvis
dc.contributor.author	Navarro-Sánchez, José
dc.contributor.author	Escorcia-Ariza, Garin
dc.contributor.author	Mattera, Michele
dc.contributor.author	Arnold, Thomas
dc.contributor.author	Rawle, Jonathan
dc.contributor.author	Tatay Aguilar, Sergio
dc.contributor.author	Coronado Miralles, Eugenio
dc.contributor.author	Martí Gastaldo, Carlos
dc.date.accessioned	2019-01-18T15:20:05Z
dc.date.available	2019-01-18T15:20:05Z
dc.date.issued	2018
dc.identifier.uri	http://hdl.handle.net/10550/68564
dc.description.abstract	Though generally considered insulating, recent progress on the discovery of conductive porous metal-organic frameworks (MOFs) offers new opportunities for their integration as electroactive components in electronic devices. Compared to classical semiconductors, these metal-organic hybrids combine the crystallinity of inorganic materials with easier chemical functionalization and processability. Still, future development depends on the ability to produce high-quality films with fine control over their orientation, crystallinity, homogeneity, and thickness. Here self-assembled monolayer substrate modification and bottom-up techniques are used to produce preferentially oriented, ultrathin, conductive films of Cu-CAT-1. The approach permits to fabricate and study the electrical response of MOF-based devices incorporating the thinnest MOF film reported thus far (10 nm thick).
dc.language.iso	eng
dc.relation.ispartof	Advanced Materials, 2018, vol. 30, num. 10, p. 1704291
dc.rights.uri	info:eu-repo/semantics/openAccess
dc.source	Rubio-Giménez, Víctor Galbiati, Marta Castells-Gil, Javier Almora-Barrios, Neyvis Navarro-Sánchez, José Escorcia-Ariza, Garin Mattera, Michele Arnold, Thomas Rawle, Jonathan Tatay Aguilar, Sergio Coronado Miralles, Eugenio Martí Gastaldo, Carlos 2018 Bottom‐Up Fabrication of Semiconductive Metal-Organic Framework Ultrathin Films Advanced Materials 30 10 1704291
dc.subject	Conductivitat elèctrica
dc.subject	Química organometàl·lica
dc.title	Bottom‐Up Fabrication of Semiconductive Metal-Organic Framework Ultrathin Films
dc.type	info:eu-repo/semantics/article
dc.date.updated	2019-01-18T15:20:05Z
dc.identifier.doi	https://doi.org/10.1002/adma.201704291
dc.identifier.idgrec	124431