Bottom‐Up Fabrication of Semiconductive Metal-Organic Framework Ultrathin Films
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Bottom‐Up Fabrication of Semiconductive Metal-Organic Framework Ultrathin Films

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Bottom‐Up Fabrication of Semiconductive Metal-Organic Framework Ultrathin Films

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dc.contributor.author Rubio-Giménez, Víctor
dc.contributor.author Galbiati, Marta
dc.contributor.author Castells-Gil, Javier
dc.contributor.author Almora-Barrios, Neyvis
dc.contributor.author Navarro-Sánchez, José
dc.contributor.author Escorcia-Ariza, Garin
dc.contributor.author Mattera, Michele
dc.contributor.author Arnold, Thomas
dc.contributor.author Rawle, Jonathan
dc.contributor.author Tatay Aguilar, Sergio
dc.contributor.author Coronado Miralles, Eugenio
dc.contributor.author Martí Gastaldo, Carlos
dc.date.accessioned 2019-01-18T15:20:05Z
dc.date.available 2019-01-18T15:20:05Z
dc.date.issued 2018
dc.identifier.uri http://hdl.handle.net/10550/68564
dc.description.abstract Though generally considered insulating, recent progress on the discovery of conductive porous metal-organic frameworks (MOFs) offers new opportunities for their integration as electroactive components in electronic devices. Compared to classical semiconductors, these metal-organic hybrids combine the crystallinity of inorganic materials with easier chemical functionalization and processability. Still, future development depends on the ability to produce high-quality films with fine control over their orientation, crystallinity, homogeneity, and thickness. Here self-assembled monolayer substrate modification and bottom-up techniques are used to produce preferentially oriented, ultrathin, conductive films of Cu-CAT-1. The approach permits to fabricate and study the electrical response of MOF-based devices incorporating the thinnest MOF film reported thus far (10 nm thick).
dc.language.iso eng
dc.relation.ispartof Advanced Materials, 2018, vol. 30, num. 10, p. 1704291
dc.rights.uri info:eu-repo/semantics/openAccess
dc.source Rubio-Giménez, Víctor Galbiati, Marta Castells-Gil, Javier Almora-Barrios, Neyvis Navarro-Sánchez, José Escorcia-Ariza, Garin Mattera, Michele Arnold, Thomas Rawle, Jonathan Tatay Aguilar, Sergio Coronado Miralles, Eugenio Martí Gastaldo, Carlos 2018 Bottom‐Up Fabrication of Semiconductive Metal-Organic Framework Ultrathin Films Advanced Materials 30 10 1704291
dc.subject Conductivitat elèctrica
dc.subject Química organometàl·lica
dc.title Bottom‐Up Fabrication of Semiconductive Metal-Organic Framework Ultrathin Films
dc.type info:eu-repo/semantics/article
dc.date.updated 2019-01-18T15:20:05Z
dc.identifier.doi https://doi.org/10.1002/adma.201704291
dc.identifier.idgrec 124431

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