Chemical Engineering of Photoactivity in Heterometallic Titanium-Organic Frameworks by Metal Doping
NAGIOS: RODERIC FUNCIONANDO

Chemical Engineering of Photoactivity in Heterometallic Titanium-Organic Frameworks by Metal Doping

DSpace Repository

Chemical Engineering of Photoactivity in Heterometallic Titanium-Organic Frameworks by Metal Doping

Show simple item record

dc.contributor.author Castells-Gil, Javier
dc.contributor.author Padial, Natalia M.
dc.contributor.author Almora-Barrios, Neyvis
dc.contributor.author Albero, Josep
dc.contributor.author Ruiz-Salvador, A. Rabdel
dc.contributor.author González-Platas, Javier
dc.contributor.author García, Hermenegildo
dc.contributor.author Martí Gastaldo, Carlos
dc.date.accessioned 2019-01-17T16:10:03Z
dc.date.available 2019-01-17T16:10:03Z
dc.date.issued 2018
dc.identifier.uri http://hdl.handle.net/10550/68521
dc.description.abstract We report a new family of titanium-organic frameworks that enlarges the limited number of crystalline, porous materials available for this metal. They are chemically robust and can be prepared as single crystals at multi‐gram scale from multiple precursors. Their heterometallic structure enables engineering of their photoactivity by metal doping rather than by linker functionalization. Compared to other methodologies based on the post‐synthetic metallation of MOFs, our approach is well‐fitted for controlling the positioning of dopants at an atomic level to gain more precise control over the band‐gap and electronic properties of the porous solid. Changes in the band‐gap are also rationalized with computational modelling and experimentally confirmed by photocatalytic H2 production.
dc.language.iso eng
dc.relation.ispartof Angewandte Chemie, 2018, vol. 57, num. 28, p. 8453-8457
dc.rights.uri info:eu-repo/semantics/openAccess
dc.source Castells-Gil, Javier Padial, Natalia M. Almora-Barrios, Neyvis Albero, Josep Ruiz-Salvador, A. Rabdel González-Platas, Javier García, Hermenegildo Martí Gastaldo, Carlos 2018 Chemical Engineering of Photoactivity in Heterometallic Titanium-Organic Frameworks by Metal Doping Angewandte Chemie 57 28 8453 8457
dc.subject Química organometàl·lica
dc.subject Titani
dc.title Chemical Engineering of Photoactivity in Heterometallic Titanium-Organic Frameworks by Metal Doping
dc.type info:eu-repo/semantics/article
dc.date.updated 2019-01-17T16:10:04Z
dc.identifier.doi https://doi.org/10.1002/anie.201802089
dc.identifier.idgrec 129360
dc.embargo.terms 5 months
dc.embargo.terms 2019-06-17

View       (2.139Mb)

This item appears in the following Collection(s)

Show simple item record

Search DSpace

Advanced Search

Browse

Statistics