Gas confinement in compartmentalized coordination polymers for highly selective sorption
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Gas confinement in compartmentalized coordination polymers for highly selective sorption

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Gas confinement in compartmentalized coordination polymers for highly selective sorption

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dc.contributor.author Giménez Marqués, Mónica
dc.contributor.author Calvo Galve, Néstor
dc.contributor.author Palomino, Miguel
dc.contributor.author Valencia, Susana
dc.contributor.author Rey, Fernando
dc.contributor.author Sastre, Germán
dc.contributor.author Vitórica-Yrezábal, Iñigo J.
dc.contributor.author Jiménez Ruiz, Mónica
dc.contributor.author Rodríguez-Velamazán, J. A.
dc.contributor.author González, Miguel A.
dc.contributor.author Jordá, José L.
dc.contributor.author Coronado Miralles, Eugenio
dc.contributor.author Mínguez Espallargas, Guillermo
dc.date.accessioned 2019-01-14T15:10:22Z
dc.date.available 2019-01-14T15:10:22Z
dc.date.issued 2017
dc.identifier.uri http://hdl.handle.net/10550/68470
dc.description.abstract Discrimination between different gases is an essential aspect for industrial and environmental applications involving sensing and separation. Several classes of porous materials have been used in this context, including zeolites and more recently MOFs. However, to reach high selectivities for the separation of gas mixtures is a challenging task that often requires the understanding of the specific interactions established between the porous framework and the gases. Here we propose an approach to obtain an enhanced selectivity based on the use of compartmentalized coordination polymers, named CCP-1 and CCP-2, which are crystalline materials comprising isolated discrete cavities. These compartmentalized materials are excellent candidates for the selective separation of CO2 from methane and nitrogen. A complete understanding of the sorption process is accomplished with the use of complementary experimental techniques including X-ray diffraction, adsorption studies, inelastic- and quasi-elastic neutron scattering, magnetic measurements and molecular dynamics calculations.
dc.language.iso eng
dc.relation.ispartof Chemical Science, 2017, vol. 8, p. 3109-3120
dc.rights.uri info:eu-repo/semantics/openAccess
dc.source Giménez Marqués, Mónica Calvo Galve, Néstor Palomino, Miguel Valencia, Susana Rey, Fernando Sastre, Germán Vitórica-Yrezábal, Iñigo J. Jiménez Ruiz, Mónica Rodríguez-Velamazán, J. A. González, Miguel A. Jordá, José L. Coronado Miralles, Eugenio Mínguez Espallargas, Guillermo 2017 Gas confinement in compartmentalized coordination polymers for highly selective sorption Chemical Science 8 3109 3120
dc.subject Solucions polimèriques
dc.subject Química
dc.title Gas confinement in compartmentalized coordination polymers for highly selective sorption
dc.type info:eu-repo/semantics/article
dc.date.updated 2019-01-14T15:10:23Z
dc.identifier.doi https://doi.org/10.1039/c6sc05122g
dc.identifier.idgrec 119851

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