Surface Functionalization of Metal−Organic Framework Crystals with Catechol Coatings for Enhanced Moisture Tolerance
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Surface Functionalization of Metal−Organic Framework Crystals with Catechol Coatings for Enhanced Moisture Tolerance

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Surface Functionalization of Metal−Organic Framework Crystals with Catechol Coatings for Enhanced Moisture Tolerance

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dc.contributor.author Castells-Gil, Javier
dc.contributor.author Novio, Fernando
dc.contributor.author Padial, Natalia M.
dc.contributor.author Tatay Aguilar, Sergio
dc.contributor.author Ruiz-Molina, Daniel
dc.contributor.author Martí Gastaldo, Carlos
dc.date.accessioned 2019-01-11T14:52:14Z
dc.date.available 2019-01-11T14:52:14Z
dc.date.issued 2017
dc.identifier.uri http://hdl.handle.net/10550/68467
dc.description.abstract Robust catechol coatings for enhanced moisture tolerance can be produced in one step by direct reaction of HKUST with synthetic catechols. We ascribe the rapid formation of homogeneous coatings around the MOF particles to the biomimetic catalytic activity of Cu(II) dimers in the external surface of the crystals. Use of fluorinated catechols results in hydrophobic, permeable coatings that protect HKUST from water degradation whilst retaining close to 100 % of its original sorption capacity.
dc.language.iso eng
dc.relation.ispartof Acs Applied Materials & Interfaces, 2017, vol. 9, num. 51, p. 44641-44648
dc.rights.uri info:eu-repo/semantics/openAccess
dc.source Castells-Gil, Javier Novio, Fernando Padial, Natalia M. Tatay Aguilar, Sergio Ruiz-Molina, Daniel Martí Gastaldo, Carlos 2017 Surface Functionalization of Metal−Organic Framework Crystals with Catechol Coatings for Enhanced Moisture Tolerance Acs Applied Materials & Interfaces 9 51 44641 44648
dc.subject Materials
dc.subject Química
dc.title Surface Functionalization of Metal−Organic Framework Crystals with Catechol Coatings for Enhanced Moisture Tolerance
dc.type info:eu-repo/semantics/article
dc.date.updated 2019-01-11T14:52:14Z
dc.identifier.doi https://doi.org/10.1021/acsami.7b15564
dc.identifier.idgrec 124035

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