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Rapid and Complete Surface Modification with Strain‐Promoted Oxidation‐Controlled Cyclooctyne‐1,2‐Quinone Cycloaddition (SPOCQ)

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Rapid and Complete Surface Modification with Strain‐Promoted Oxidation‐Controlled Cyclooctyne‐1,2‐Quinone Cycloaddition (SPOCQ)

dc.contributor.author	Sen, Rickdeb
dc.contributor.author	Escorihuela Fuentes, Jorge
dc.contributor.author	van Delft, Floris L.
dc.contributor.author	Zuilhof, Han
dc.date.accessioned	2018-09-05T13:58:41Z
dc.date.available	2018-09-05T13:58:41Z
dc.date.issued	2017
dc.identifier.uri	http://hdl.handle.net/10550/67411
dc.description.abstract	Strain‐promoted oxidation‐controlled cyclooctyne‐1,2‐quinone cycloaddition (SPOCQ) between functionalized bicyclo[6.1.0]non‐4‐yne (BCN) and surface‐bound quinones revealed an unprecedented 100 % conjugation efficiency. In addition, monitoring by direct analysis in real time mass spectrometry (DART‐MS) revealed the underlying kinetics and activation parameters of this immobilization process in dependence on its microenvironment.
dc.language.iso	eng
dc.relation.ispartof	Angewandte Chemie, 2017, vol. 56, num. 12, p. 3299-3303
dc.rights.uri	info:eu-repo/semantics/openAccess
dc.source	Sen, Rickdeb Escorihuela Fuentes, Jorge van Delft, Floris L. Zuilhof, Han 2017 Rapid and Complete Surface Modification with Strain‐Promoted Oxidation‐Controlled Cyclooctyne‐1,2‐Quinone Cycloaddition (SPOCQ) Angewandte Chemie 56 12 3299 3303
dc.subject	Química orgànica
dc.subject	Química de superfícies
dc.title	Rapid and Complete Surface Modification with Strain‐Promoted Oxidation‐Controlled Cyclooctyne‐1,2‐Quinone Cycloaddition (SPOCQ)
dc.type	info:eu-repo/semantics/article
dc.date.updated	2018-09-05T13:58:42Z
dc.identifier.doi	https://doi.org/10.1002/anie.201612037
dc.identifier.idgrec	126744