Iodide-photocatalyzed reduction of carbon dioxide to formic acid with thiols and hydrogen sulfide
NAGIOS: RODERIC FUNCIONANDO

Iodide-photocatalyzed reduction of carbon dioxide to formic acid with thiols and hydrogen sulfide

DSpace Repository

Iodide-photocatalyzed reduction of carbon dioxide to formic acid with thiols and hydrogen sulfide

Show full item record

View       (404.4Kb)

    
Berton, Mateo Otao; Mello, Rossella C. C.; González Núñez, María Elena
This document is a artículoDate2016

Este documento está disponible también en : http://hdl.handle.net/10550/57676
The photolysis of iodide anions promotes the reaction of carbon dioxide with hydrogen sulfide or thiols to quantitatively yield formic acid and sulfur or disulfides. The reaction proceeds in acetonitrile and aqueous solutions, at atmospheric pressure and room temperature by irradiation using a low-pressure mercury lamp. This transition-metal-free photocatalytic process for CO2 capture coupled with H2S removal may have been relevant as a prebiotic carbon dioxide fixation.

    Berton, Mateo Otao Mello, Rossella C. C. González Núñez, María Elena 2016 Iodide-photocatalyzed reduction of carbon dioxide to formic acid with thiols and hydrogen sulfide Chemsuschem 9 24 3397 3400
http://dx.doi.org/10.1002/cssc.201601285

This item appears in the following Collection(s)

Show full item record

Search DSpace

Advanced Search

Browse

Statistics