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Unexpected photochemistry and charge-transfer complexes of [CB11H12]2 carborane
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Unexpected photochemistry and charge-transfer complexes of [CB11H12]2 carborane
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| Llabrés y Xamena, Francesc X.; Teruel, Laura; Galletero Pedroche, M.Sales; Corma, Avelino; García, Hermenegildo | |
| This document is a artículo publicadoDate2008 | |
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Este documento está disponible también en : http://hdl.handle.net/10550/16790 |
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| Although the [CB11H12]¯carborane does not exhibit an absorption band inUV, its triplet excited state can be generated upon 308 nm laser excitation; also unexpectedly carborane acts as electron donor forming a charge transfer complex with methylviologen that upon illumination gives rise to viologen radical cation. | |
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LLABRÉS Y XAMENA, Francesc X. ; Teruel, Laura ; Galletero Pedroche, M.Sales ; Corma, Avelino ; García, Hermenegildo, 2008, Unexpected photochemistry and charge-transfer complexes of [CB11H12]2 carborane, Chemical communications, vol. 2008, p. 499-501 |
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| http://www.rsc.org/ej/CC/2008/b715303a.pdf |
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23 - Química [811]