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Enantio- and diastereocontrol in intermolecular cyclopropanation reaction of styrene catalyzed by dirhodium(II) complexes with bulky ortho-metalated aryl phosphines
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Enantio- and diastereocontrol in intermolecular cyclopropanation reaction of styrene catalyzed by dirhodium(II) complexes with bulky ortho-metalated aryl phosphines
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| Estevan Estevan, Francisco; Lahuerta Peña, Pascual; Lloret Fillol, Julio; Sanau Torrecilla, Mercedes; Úbeda Picot, M. Ángeles; Vila Gomez, Jaume Llorenc | |
| This document is a artículo publicadoDate2004 | |
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Este documento está disponible también en : http://hdl.handle.net/10550/16768 |
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| Enantiomerically pure dirhodium(II) complexes with ortho-metalated p-substituted aryl phosphines have been shown to be enantio- and diastereoselective in the cyclopropanation of styrene by ethyl diazoacetate. Enantioselectivities up to 91% and diastereoselectivities up to 90% are observed for ethyl cis-2-phenylcyclopropanecarboxylate. | |
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ESTEVAN ESTEVAN, Francisco ; Lahuerta Peña, Pascual ; Lloret Fillol, Julio ; Sanau Torrecilla, Mercedes ; Ubeda Picot, M Angeles ; Vila Gomez, Jaume Llorenc, 2004, Enantio- and diastereocontrol in intermolecular cyclopropanation reaction of styrene catalyzed by dirhodium(II) complexes with bulky ortho-metalated aryl phosphines, Chemical communications, vol. 2004, p. 2408-2409 |
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| http://www.rsc.org/ej/CC/2004/b408856e.pdf |
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23 - Química [964]