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A novel high-spin heterometallic Ni12K4 cluster incorporating large Ni–azide circles and an in situ cyanomethylated di-2-pyridyl ketone

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A novel high-spin heterometallic Ni12K4 cluster incorporating large Ni–azide circles and an in situ cyanomethylated di-2-pyridyl ketone

dc.contributor.author	Tong, Ming-Liang
dc.contributor.author	Monfort, Monserrat
dc.contributor.author	Clemente Juan, Juan Modesto
dc.contributor.author	Chen, Xiao-Ming
dc.contributor.author	Ohba, Masaaki
dc.contributor.author	Kitagawa, Susumu
dc.date.accessioned	2010-07-30T11:08:42Z
dc.date.available	2010-07-30T11:08:42Z
dc.date.issued	2005
dc.identifier.uri	http://hdl.handle.net/10550/16747
dc.description.abstract	Reaction of di-2-pyridyl ketone (dpk) with nickel acetate and azide in the presence of potassium tert-butylate as a catalytic base generates the title compound, which contains the largest [Ni(m1,1-N3)]6 circles in the discrete ferromagnetically-coupled MII–azide cluster family, and shows an unprecedented in situ cyanomethylation of ketone.	en
dc.language.iso	en	en
dc.relation	http://www.rsc.org/ej/CC/2005/b415431b.pdf	en
dc.source	TONG, Ming-Liang ; Monfort, Monserrat ; Clemente Juan, Juan Modesto ; Chen, Xiao-Ming ; Ohba, Masaaki ; Kitagawa, Susumu, 2005, A novel high-spin heterometallic Ni12K4 cluster incorporating large Ni–azide circles and an in situ cyanomethylated di-2-pyridyl ketone, Chemical communications, vol. 2005, p. 233-235	en
dc.subject	Cyanomethylation of ketone ; Potassium tert-butylate ; Ferromagnetically-coupled Mll-azide ; Nickel acetate ; Novel	en
dc.title	A novel high-spin heterometallic Ni12K4 cluster incorporating large Ni–azide circles and an in situ cyanomethylated di-2-pyridyl ketone	en
dc.type	journal article	es_ES
dc.subject.unesco	UNESCO::QUÍMICA	en
dc.subject.unesco	UNESCO::QUÍMICA::Química inorgánica	en
dc.identifier.doi	10.1039/b415431b	en
dc.description.private	Clemente Juan, Juan Modesto, Juan.M.Clemente@uv.es	en
dc.identifier.idgrec	014607	en
dc.type.hasVersion	VoR	es_ES