NAGIOS: RODERIC FUNCIONANDO
A novel high-spin heterometallic Ni12K4 cluster incorporating large Ni–azide circles and an in situ cyanomethylated di-2-pyridyl ketone
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A novel high-spin heterometallic Ni12K4 cluster incorporating large Ni–azide circles and an in situ cyanomethylated di-2-pyridyl ketone
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| Tong, Ming-Liang; Monfort, Monserrat; Clemente Juan, Juan Modesto Perfil; Chen, Xiao-Ming; Ohba, Masaaki; Kitagawa, Susumu | |
| This document is a artículo publicadoDate2005 | |
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Este documento está disponible también en : http://hdl.handle.net/10550/16747 |
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| Reaction of di-2-pyridyl ketone (dpk) with nickel acetate and azide in the presence of potassium tert-butylate as a catalytic base generates the title compound, which contains the largest [Ni(m1,1-N3)]6 circles in the discrete ferromagnetically-coupled MII–azide cluster family, and shows an unprecedented in situ cyanomethylation of ketone. | |
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TONG, Ming-Liang ; Monfort, Monserrat ; Clemente Juan, Juan Modesto ; Chen, Xiao-Ming ; Ohba, Masaaki ; Kitagawa, Susumu, 2005, A novel high-spin heterometallic Ni12K4 cluster incorporating large Ni–azide circles and an in situ cyanomethylated di-2-pyridyl ketone, Chemical communications, vol. 2005, p. 233-235 |
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| http://www.rsc.org/ej/CC/2005/b415431b.pdf |
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23 - Química [962]