From over-stoichiometric to sub-stoichiometric enantioselective protonation with 2-sulfinyl alcohols: a view in perspective
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From over-stoichiometric to sub-stoichiometric enantioselective protonation with 2-sulfinyl alcohols: a view in perspective

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From over-stoichiometric to sub-stoichiometric enantioselective protonation with 2-sulfinyl alcohols: a view in perspective

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dc.contributor.author Medio Simón, Mercedes
dc.contributor.author Alemán López, Pedro Antonio
dc.contributor.author Cuenca González, Ana Belén
dc.contributor.author Gil Tomás, Jesús Javier
dc.contributor.author Rodriguez, Nuria
dc.contributor.author Asensio Aguilar, Gregorio
dc.date.accessioned 2010-06-08T10:27:12Z
dc.date.available 2010-06-08T10:27:12Z
dc.date.issued 2005
dc.identifier.uri http://hdl.handle.net/10550/12897
dc.description.abstract A general study of the enantioselective protonation of prochiral enolates with 2-sulfinyl alcohols is reported. The modification of reaction conditions to reduce drastically the amount of chiral proton source needed to obtain a good enantiomeric excess is reported. The effects of the different factors controlling the stereoselectivity are clearly established. Different protocols for enolate generation are compared. en
dc.language.iso en en
dc.relation http://www.arkat-usa.org/get-file/18922/ en
dc.source Medio Simón, Mercedes ; Aleman Lopez, Pedro Antonio ; Cuenca Gonzalez, Ana Belen ; Gil Tomás, Jesús Javier ; Rodriguez, Nuria ; Asensio Aguilar, Gregorio ; 2005, From over-stoichiometric to sub-stoichiometric enantioselective protonation with 2-sulfinyl alcohols: a view in perspective, Arkivoc, vol. 2005, no. IX, p. 266-286 en
dc.subject Enolates ; Enantioselective protonation ; Sulfinyl alcohols en
dc.title From over-stoichiometric to sub-stoichiometric enantioselective protonation with 2-sulfinyl alcohols: a view in perspective en
dc.type info:eu-repo/semantics/article en
dc.type info:eu-repo/semantics/publishedVersion en
dc.subject.unesco UNESCO::QUÍMICA en
dc.subject.unesco UNESCO::QUÍMICA::Química orgánica en
dc.description.private Medio Simon, Mercedes, Mercedes.Medio@uv.es ; Aleman Lopez, Pedro Antonio, Pedro.Aleman@uv.es ; Gil Tomas, Jesus Javier, Jesus.J.Gil@uv.es ; Asensio, Aguilar Gregorio, Gregorio.Asensio@uv.es en
dc.identifier.idgrec 027487 en

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