NAGIOS: RODERIC FUNCIONANDO
Pyridylcarbene formation by thermal decomposition of 7-bromo-3-methyl-[1,2,3]triazolo[1,5-a]pyridine under pressure
DSpace Repository
- DSpace Home
- Investigació
- e-prints
- 23 - Química
- View Item
Pyridylcarbene formation by thermal decomposition of 7-bromo-3-methyl-[1,2,3]triazolo[1,5-a]pyridine under pressure
|
View
|
| Abarca González, Belén; Ballesteros Campos, Rafael; Blanco, Fernando | |
| This document is a artículo publicadoDate2007 | |
|
Este documento está disponible también en : http://hdl.handle.net/10550/12890 |
|
| 7-Bromo-3-methyl-[1,2,3]triazolo[1,5-a]pyridine 1 at 1.7 atm and 100ºC decompose to form a pyridylcarbene intermediate by nitrogen expulsion. The carbene stabilization give 2-bromo-6- vinylpyridine 2, 1-(6-bromopyridin-2-yl)ethanol 3, 1-(6-Bromopyridin-2-yl)ethanone 4, 2- bromo-6-[2-(6-bromopyridin-2-yl)-2-methyl-trans-cyclopropyl]pyridine 5, and 2-bromo-6-[2-(6- bromopyridin-2-yl)-2-methyl-cis-cyclopropyl]pyridine 6. | |
|
ABARCA GONZALEZ, Belen ; Ballesteros Campos, Rafael ; Blanco, Fernando, 2007, Pyridylcarbene formation by thermal decomposition of 7-bromo-3-methyl-[1,2,3]triazolo[1,5-a]pyridine under pressure, Arkivoc, vol. 2007, no. IV, p. 297-303 |
|
| http://www.arkat-usa.org/get-file/18979/ |
This item appears in the following Collection(s)
-
23 - Química [78]