NAGIOS: RODERIC FUNCIONANDO

Addition of dianions of carboxylic acids to imines. Influence of the acid in the outcome of the reaction

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Addition of dianions of carboxylic acids to imines. Influence of the acid in the outcome of the reaction

dc.contributor.author	Gil Grau, Salvador
dc.contributor.author	Parra Alvarez, Margarita
dc.contributor.author	Rodriguez Abad, Pablo
dc.date.accessioned	2010-06-08T10:14:27Z
dc.date.available	2010-06-08T10:14:27Z
dc.date.issued	2009
dc.identifier.uri	http://hdl.handle.net/10550/12882
dc.description.abstract	The addition of different carboxylic acids dianions to N-benzylidenebenzeneamine have been studied. The outcome of the reaction depends on the acid. Saturated ones lead to β-aminoacids with good yields and syn-selectivity whereas α,β-unsaturated ones lead to α− and γ− regioisomers with a regioselectivity that depends on the steric hindrance around the reactive centre. From some of these unsaturated acids, polyunsaturated carboxylic acids can be obtained as a change in the reaction conditions lead to the in situ elimination of aniline. From o-methyl aromatic acids δ-aminoacids are isolated with uneven results. Those derived from six member arene carboxylic acids give, on standing, dihydro-2-pyridones as the sole product.	en
dc.language.iso	en	en
dc.relation	http://www.arkat-usa.org/get-file/29567/	en
dc.source	GIL GRAU, Salvador ; Parra Alvarez, Margarita ; Rodriguez Abad, Pablo, 2009, Addition of dianions of carboxylic acids to imines. Influence of the acid in the outcome of the reaction, Arkivoc, vol. 2009, no. XI, p.172-184	en
dc.subject	Dianions ; Imines ; Regioselectivity ; Diastereoselectivity	en
dc.title	Addition of dianions of carboxylic acids to imines. Influence of the acid in the outcome of the reaction	en
dc.type	info:eu-repo/semantics/article	en
dc.type	info:eu-repo/semantics/publishedVersion	en
dc.subject.unesco	UNESCO::QUÍMICA	en
dc.subject.unesco	UNESCO::QUÍMICA::Química orgánica	en
dc.description.private	Gil Grau, Salvador, Salvador.Gil@uv.es, Parra Alvarez, Margarita, Margarita.Parra@uv.es, Rodriguez Abad, Pablo, roapa@alumni.uv.es	en
dc.identifier.idgrec	052739	en