Lattice opening upon bulk reductive covalent functionalization of black phosphorus
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Lattice opening upon bulk reductive covalent functionalization of black phosphorus

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Lattice opening upon bulk reductive covalent functionalization of black phosphorus

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Wild, Stefan; Fickert, Michael; Mitrovic, Aleksandra; Lloret, Vicent; Neiss, Christian; Vidal-Moya, Alejandro; Rivero‐Crespo, Miguel Ángel; Leyva-Pérez, Antonio; Werbach, Katharina; Peterlik, Herwig; Grabau, Mathias; Wittkämper, Haiko; Papp, Christian; Steinrück, Peter; Pichler, Thomas; Görling, Andreas; Hauke, Frank; Abellán Sáez, Gonzalo; Hirsch, Andreas
This document is a artículoDate2019
The chemical bulk reductive covalent functionalization of thin‐layer black phosphorus (BP) using BP intercalation compounds has been developed. Through effective reductive activation, covalent functionalization of the charged BP by reaction with organic alkyl halides is achieved. Functionalization was extensively demonstrated by means of several spectroscopic techniques and DFT calculations; the products showed higher functionalization degrees than those obtained by neutral routes.

    Wild, Stefan Fickert, Michael Mitrovic, Aleksandra Lloret, Vicent Neiss, Christian Vidal-Moya, Alejandro Rivero&#8208Crespo, Miguel Ángel Leyva-Pérez, Antonio Werbach, Katharina Peterlik, Herwig Grabau, Mathias Wittkämper, Haiko Papp, Christian Steinrück, Peter Pichler, Thomas Görling, Andreas Hauke, Frank Abellán Sáez, Gonzalo Hirsch, Andreas 2019 Lattice opening upon bulk reductive covalent functionalization of black phosphorus Angewandte Chemie 58 17 5763 5768
https://doi.org/10.1002/anie.201811181

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