Enantioselective addition of Et2Zn to seven-membered cyclic imines catalyzed by a (R)-VAPOL-Zn(II) complex
NAGIOS: RODERIC FUNCIONANDO

Enantioselective addition of Et2Zn to seven-membered cyclic imines catalyzed by a (R)-VAPOL-Zn(II) complex

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Enantioselective addition of Et2Zn to seven-membered cyclic imines catalyzed by a (R)-VAPOL-Zn(II) complex

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De Munck, Lode; Sukowski, Verena; Vila Descals, Carlos; Pedro, José Ramón
This document is a artículoDate2017
Various substituted dibenzo[b,f][1,4]oxazepines underwent an enantioselective alkylation with Et2Zn catalyzed by a (R)-VAPOL-Zn(II) complex. The corresponding chiral 11-ethyl-10,11-dihydrodibenzo[b,f][1,4]oxazepine derivatives were obtained with good yields and moderate enantioselectivities. This represents the first example of enantioselective addition of Et2Zn to cyclic aldimines.

    De Munck, Lode Sukowski, Verena Vila Descals, Carlos Pedro, José Ramón 2017 Enantioselective addition of Et2Zn to seven-membered cyclic imines catalyzed by a (R)-VAPOL-Zn(II) complex Tetrahedron Letters 58 34 3358 3361
https://doi.org/10.1016/j.tetlet.2017.07.042

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