Multivariate Metal-Organic Frameworks for the Simultaneous Capture of Organic and Inorganic Contaminants from Water
NAGIOS: RODERIC FUNCIONANDO

Multivariate Metal-Organic Frameworks for the Simultaneous Capture of Organic and Inorganic Contaminants from Water

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Multivariate Metal-Organic Frameworks for the Simultaneous Capture of Organic and Inorganic Contaminants from Water

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dc.contributor.author Mon Conejero, Marta
dc.contributor.author Bruno, Rosaria
dc.contributor.author Tiburcio, Estefanía
dc.contributor.author Viciano-Chumillas, Marta
dc.contributor.author Kalinke, Lucas H. G.
dc.contributor.author Ferrando Soria, Jesús
dc.contributor.author Armentano, Donatella
dc.contributor.author Pardo Marín, Emilio
dc.date.accessioned 2019-12-04T14:21:21Z
dc.date.available 2020-08-08T04:45:05Z
dc.date.issued 2019
dc.identifier.uri https://hdl.handle.net/10550/72382
dc.description.abstract We report a new water-stable multivariate (MTV) Metal-Organic Framework (MOF) prepared by combining two different oxamide-based metalloligands derived from the natural amino acids L-serine and L-methionine. This unique material features hexagonal channels decorated with two types of flexible and functional 'arms' (-CH2OH and -CH2CH2SCH3) capable to act, synergistically, for the simultaneous and efficient removal of both inorganic (heavy metals like Hg2+, Pb2+ and Tl+) and organic (dyes such as Pyronin Y, Auramine O, Brilliant Green and Methylene Blue) contaminants and, in addition, this MTV-MOF is completely reusable. Single-crystal X-ray diffraction (SCXRD) measurements allowed to solve the crystal structure of a host-guest adsorbate, containing both HgCl2 and Methylene Blue, and offered unprecedented snapshots about this unique dual capture process. This is the very first time that a MOF can be used for the removal of all sorts of pollutants from water resources, thus opening new perspectives for this emerging type of MTV-MOFs.
dc.language.iso eng
dc.relation.ispartof Journal of the American Chemical Society, 2019, vol. 141, num. 34, p. 13601-13609
dc.rights.uri info:eu-repo/semantics/openAccess
dc.source Mon Conejero, Marta Bruno, Rosaria Tiburcio, Estefanía Viciano-Chumillas, Marta Kalinke, Lucas H. G. Ferrando Soria, Jesús Armentano, Donatella Pardo Marín, Emilio 2019 Multivariate Metal-Organic Frameworks for the Simultaneous Capture of Organic and Inorganic Contaminants from Water Journal of the American Chemical Society 141 34 13601 13609
dc.subject Química organometàl·lica
dc.subject Aigua Contaminació
dc.title Multivariate Metal-Organic Frameworks for the Simultaneous Capture of Organic and Inorganic Contaminants from Water
dc.type info:eu-repo/semantics/article
dc.date.updated 2019-12-04T14:21:21Z
dc.identifier.doi https://doi.org/10.1021/jacs.9b06250
dc.identifier.idgrec 135288

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