Direct visualization of pyrrole reactivity by confined oxidation in a Cyclodextrin Metal‐Organic Framework
NAGIOS: RODERIC FUNCIONANDO

Direct visualization of pyrrole reactivity by confined oxidation in a Cyclodextrin Metal‐Organic Framework

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Direct visualization of pyrrole reactivity by confined oxidation in a Cyclodextrin Metal‐Organic Framework

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Núñez-López, Alejandro; Galbiati, Marta; Padial, Natalia M.; Ganivet, Carolina R.; Tatay Aguilar, Sergio; Pardo Marín, Emilio; Armentano, Donatella; Martí Gastaldo, Carlos
This document is a artículoDate2019
Metal-organic frameworks can be used as porous templates to exert control over polymerization reactions. Shown here are the possibilities offered by these crystalline, porous nanoreactors to capture highly‐reactive intermediates for a better understanding of the mechanism of polymerization reactions. By using a cyclodextrin framework the polymerization of pyrrole is restricted, capturing the formation of terpyrrole cationic intermediates. Single‐crystal X‐ray diffraction is used to provide definite information on the supramolecular interactions that induce the formation and stabilization of a conductive array of cationic complexes.

    Núñez-López, Alejandro Galbiati, Marta Padial, Natalia M. Ganivet, Carolina R. Tatay Aguilar, Sergio Pardo Marín, Emilio Armentano, Donatella Martí Gastaldo, Carlos 2019 Direct visualization of pyrrole reactivity by confined oxidation in a Cyclodextrin Metal‐Organic Framework Angewandte Chemie 58 27 9179 9183
https://doi.org/10.1002/anie.201904890

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