Breathing-Dependent Redox Activity in a Tetrathiafulvalene-Based Metal-Organic Framework
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Breathing-Dependent Redox Activity in a Tetrathiafulvalene-Based Metal-Organic Framework

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Breathing-Dependent Redox Activity in a Tetrathiafulvalene-Based Metal-Organic Framework

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dc.contributor.author Souto, Manuel
dc.contributor.author Romero Pascual, Jorge
dc.contributor.author Calbo Roig, Joaquín
dc.contributor.author Vitórica-Yrezábal, Iñigo J.
dc.contributor.author Zafra, José L.
dc.contributor.author Casado, Juan
dc.contributor.author Ortí Guillén, Enrique
dc.contributor.author Walsh, Aron
dc.contributor.author Mínguez Espallargas, Guillermo
dc.date.accessioned 2019-01-18T14:50:15Z
dc.date.available 2019-01-18T14:50:15Z
dc.date.issued 2018
dc.identifier.uri http://hdl.handle.net/10550/68563
dc.description.abstract 'Breathing' metal-organic frameworks (MOFs) which involve changes in their structural and physical properties upon an external stimulus are an interesting class of crystalline materials due to their range of potential applications including chemical sensors. The addition of redox activity opens up a new pathway for multi-functional 'breathing' frameworks. Herein we report the continuous breathing behavior of a tetrathiafulvalene (TTF)-based MOF, namely MUV-2, showing a reversible swelling (up to ca. 40% of the volume cell) upon solvent adsorption. Importantly, the planarity of the TTF linkers is influenced by the breathing behavior, directly impacting on their electrochemical properties, thus opening the way for the development of new electrochemical sensors. Quantum chemical calculations and Raman spectroscopy have been used to provide insights into the tunability of the oxidation potential.
dc.language.iso eng
dc.relation.ispartof Journal of the American Chemical Society, 2018, vol. 140, num. 33, p. 10562-10569
dc.rights.uri info:eu-repo/semantics/openAccess
dc.source Souto, Manuel Romero Pascual, Jorge Calbo Roig, Joaquín Vitórica-Yrezábal, Iñigo J. Zafra, José L. Casado, Juan Ortí Guillén, Enrique Walsh, Aron Mínguez Espallargas, Guillermo 2018 Breathing-Dependent Redox Activity in a Tetrathiafulvalene-Based Metal-Organic Framework Journal of the American Chemical Society 140 33 10562 10569
dc.subject Reacció d'oxidació-reducció
dc.subject Química organometàl·lica
dc.title Breathing-Dependent Redox Activity in a Tetrathiafulvalene-Based Metal-Organic Framework
dc.type info:eu-repo/semantics/article
dc.date.updated 2019-01-18T14:50:16Z
dc.identifier.doi https://doi.org/10.1021/jacs.8b05890
dc.identifier.idgrec 126749

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