Isoreticular two-dimensional magnetic coordination polymers prepared through pre-synthetic ligand functionalization
NAGIOS: RODERIC FUNCIONANDO

Isoreticular two-dimensional magnetic coordination polymers prepared through pre-synthetic ligand functionalization

DSpace Repository

Isoreticular two-dimensional magnetic coordination polymers prepared through pre-synthetic ligand functionalization

Show simple item record

dc.contributor.author López Cabrelles, Javier
dc.contributor.author Mañas Valero, Samuel
dc.contributor.author Vitórica-Yrezábal, Iñigo J.
dc.contributor.author Bereciartua, P. J.
dc.contributor.author Rodríguez-Velamazán, J. A.
dc.contributor.author Waerenborgh, João C.
dc.contributor.author Vieira, Bruno J. C.
dc.contributor.author Davidovikj, D.
dc.contributor.author Steeneken, P. G.
dc.contributor.author Van der Zant, H.S.J.
dc.contributor.author Mínguez Espallargas, Guillermo
dc.contributor.author Coronado Miralles, Eugenio
dc.date.accessioned 2018-12-19T15:25:56Z
dc.date.available 2019-02-28T05:45:05Z
dc.date.issued 2018
dc.identifier.uri http://hdl.handle.net/10550/68320
dc.description.abstract Chemical functionalization is a powerful approach to tailor the physical and chemical properties of two-dimensional materials, increase their processability and stability, tune their functionalities and, even, create new 2D materials. This is typically achieved through post-synthetic functionalization by anchoring molecules on the surface of an exfoliated 2D crystal, but it inevitably alters the long-range structural order of the material. Here we present a pre-synthetic approach that allows the isolation of crystalline, robust, and magnetic functionalized monolayers of coordination polymers. A series of five isoreticular layered magnetic coordination polymers based on Fe(II) centres and different benzimidazole derivatives (bearing a Cl, H, CH3, Br or NH2 side group) were first prepared. On mechanical exfoliation, 2D materials are obtained that retain their long-range structural order and exhibit good mechanical and magnetic properties. This combination, together with the possibility to functionalize their surface at will, makes them good candidates to explore magnetism in the 2D limit and to fabricate mechanical resonators for selective gas sensing.
dc.language.iso eng
dc.relation.ispartof Nature Chemistry, 2018, vol. 10, p. 1001-1007
dc.rights.uri info:eu-repo/semantics/openAccess
dc.source López Cabrelles, Javier Mañas Valero, Samuel Vitórica-Yrezábal, Iñigo J. Bereciartua, P. J. Rodríguez-Velamazán, J. A. Waerenborgh, João C. Vieira, Bruno J. C. Davidovikj, D. Steeneken, P. G. Van der Zant, H.S.J. Mínguez Espallargas, Guillermo Coronado Miralles, Eugenio 2018 Isoreticular two-dimensional magnetic coordination polymers prepared through pre-synthetic ligand functionalization Nature Chemistry 10 1001 1007
dc.subject Solucions polimèriques
dc.subject Ciència dels materials
dc.title Isoreticular two-dimensional magnetic coordination polymers prepared through pre-synthetic ligand functionalization
dc.type info:eu-repo/semantics/article
dc.date.updated 2018-12-19T15:25:56Z
dc.identifier.doi https://doi.org/10.1038/s41557-018-0113-9
dc.identifier.idgrec 126986
dc.embargo.terms 2 months

View       (2.387Mb)

This item appears in the following Collection(s)

Show simple item record

Search DSpace

Advanced Search

Browse

Statistics