A highly stable and hierarchical tetrathiafulvalene-based metal-organic framework with improved performance as a solid catalyst
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A highly stable and hierarchical tetrathiafulvalene-based metal-organic framework with improved performance as a solid catalyst

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A highly stable and hierarchical tetrathiafulvalene-based metal-organic framework with improved performance as a solid catalyst

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dc.contributor.author Souto, Manuel
dc.contributor.author Santiago-Portillo, Andrea
dc.contributor.author Palomino, Miguel
dc.contributor.author Vitórica-Yrezábal, Iñigo J.
dc.contributor.author Vieira, Bruno J. C.
dc.contributor.author Waerenborgh, João C.
dc.contributor.author Valencia, Susana
dc.contributor.author Navalón, Sergio
dc.contributor.author Rey, Fernando
dc.contributor.author García, Hermenegildo
dc.contributor.author Mínguez Espallargas, Guillermo
dc.date.accessioned 2018-12-19T14:59:42Z
dc.date.available 2018-12-19T14:59:42Z
dc.date.issued 2018
dc.identifier.uri http://hdl.handle.net/10550/68319
dc.description.abstract Herein we report the synthesis of a tetrathiafulvalene (TTF)-based MOF, namely MUV-2, which shows a non-interpenetrated hierarchical crystal structure with mesoporous one-dimensional channels of ca. 3 nm and orthogonal microporous channels of ca. 1 nm. This highly stable MOF (aqueous solution with pH values ranging 2-11 and different organic solvents), possessing the well-known [Fe3(μ3-O)(COO)6] secondary building unit, has proven to be an efficient catalyst for the aerobic oxidation of dibenzothiophenes.
dc.language.iso eng
dc.relation.ispartof Chemical Science, 2018, vol. 9, p. 2413-2418
dc.rights.uri info:eu-repo/semantics/openAccess
dc.source Souto, Manuel Santiago-Portillo, Andrea Palomino, Miguel Vitórica-Yrezábal, Iñigo J. Vieira, Bruno J. C. Waerenborgh, João C. Valencia, Susana Navalón, Sergio Rey, Fernando García, Hermenegildo Mínguez Espallargas, Guillermo 2018 A highly stable and hierarchical tetrathiafulvalene-based metal-organic framework with improved performance as a solid catalyst Chemical Science 9 2413 2418
dc.subject Solucions polimèriques
dc.subject Química organometàl·lica
dc.title A highly stable and hierarchical tetrathiafulvalene-based metal-organic framework with improved performance as a solid catalyst
dc.type info:eu-repo/semantics/article
dc.date.updated 2018-12-19T14:59:42Z
dc.identifier.doi https://doi.org/10.1039/C7SC04829G
dc.identifier.idgrec 126748

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